diiodo(phenyl)stibane

Base Information

• Chemical Name: diiodo(phenyl)stibane
• CAS No.: 68972-61-2
• Molecular Formula: C₆H₅I₂Sb
• Molecular Weight: 452.665
• Mol file: 68972-61-2.mol

Synonyms:diiodo(phenyl)stibane

Chemical Property of diiodo(phenyl)stibane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of diiodo(phenyl)stibane

There total 14 articles about diiodo(phenyl)stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

dichlorophenylstibine (5035-52-9) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → diiodo(phenyl)stibane (68972-61-2)

Guidance literature:

In hydrogenchloride; byproducts: NaCl; solving SbCl2C6H5 in small amt. of concd. HCl; dropping concd. aq. NaI soln. to soln. till there is no pptn.; after modification of method of H. Schmidt, Liebigs Ann. Chem. 421 (1920, Nachdr. 1955) 174;; recrystn. from n-pentane at -60-20°C; mass spectroscopy;;

Reference yield:

phenylstibane (58266-50-5) → diiodo(phenyl)stibane (68972-61-2)

Guidance literature:

With iodine; In diethyl ether; byproducts: HI; at room temp.;

Reference yield:

dichlorophenylstibine (5035-52-9) → diiodo(phenyl)stibane (68972-61-2)

Guidance literature:

Multi-step reaction with 2 steps

1: LiBH₄ / diethyl ether

2: I₂

With LiBH₄; I₂; In diethyl ether;

upstream raw materials:

phenylstibane

dichlorophenylstibine

sodium iodide

phenylstibine oxide

Downstream raw materials:

C₆H₅Sb(OH)2

phenylstibonic acid

phenylstibine oxide

hexaphenyl-cyclo-hexastibane * benzene