N₂F⁽¹⁺⁾*AsF₆^(1-) = (N₂F)AsF₆

Base Information

• Chemical Name: N₂F⁽¹⁺⁾*AsF₆^(1-) = (N₂F)AsF₆
• CAS No.: 12005-87-7
• Molecular Formula: AsF₆*FN₂
• Molecular Weight: 235.924
• Mol file: 12005-87-7.mol

Synonyms:N₂F⁽¹⁺⁾*AsF₆^(1-) = (N₂F)AsF₆

Chemical Property of N₂F⁽¹⁺⁾*AsF₆^(1-) = (N₂F)AsF₆

Chemical Property:

Purity/Quality:

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Technology Process of N₂F⁽¹⁺⁾*AsF₆^(1-) = (N₂F)AsF₆

There total 1 articles about N₂F⁽¹⁺⁾*AsF₆^(1-) = (N₂F)AsF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

SF5NF2 (13693-10-2) + KrF(1+)*AsF6(1-)=(KrF)(AsF6) (50859-36-4) → nitrogen trifluoride (7783-54-2) + trans-1,2-difluorodiazine (13776-62-0) + N2F(1+)*AsF6(1-) = (N2F)AsF6 (12005-87-7) + krypton + sulfur(VI) hexafluoride (2551-62-4)

Guidance literature:

With HF; In hydrogen fluoride; HF (liquid); reagents were mixed at -31°C for 6.5 h, then mixt. was warmed toroom temp. for 18 h;

Reference yield: 99.0%

N2F(1+)*AsF6(1-) = (N2F)AsF6 (12005-87-7) + sodium fluoride (7681-49-4) → cis-difluorodiazene (13812-43-6)

Guidance literature:

In hydrogen fluoride; HF (liquid); (vac.); addn. of NaF to hexafluoroarsenate salt in HF, shaking at room temp.;

DOI:10.1021/ic100471s

Reference yield:

N2F(1+)*AsF6(1-) = (N2F)AsF6 (12005-87-7) + nitrosyl fluoride (7789-25-5) → NO(1+)*AsF6(1-)=NOAsF6 (18535-07-4) + cis-difluorodiazene (13812-43-6)

Guidance literature:

In neat (no solvent); addn. of FNO at -196°C, allowed to warm to -78°C, allowed to warm to room temp. over a period of 12 h; cooled to -196°C, sepn. by fractional condensation;

DOI:10.1021/ja00010a023

upstream raw materials:

SF₅NF₂

KrF⁽¹⁺⁾*AsF₆^(1-)=(KrF)(AsF₆)

Downstream raw materials:

NO⁽¹⁺⁾*AsF₆^(1-)=NOAsF₆

cis-difluorodiazene

Refernces