Cycloheptatriene molybdenum tricarbonyl

Base Information

• Chemical Name: Cycloheptatriene molybdenum tricarbonyl
• CAS No.: 12125-77-8
• Molecular Formula: C10H8 Mo O3
• Molecular Weight: 272.12
• European Community (EC) Number: 235-197-4
• Wikipedia: Cycloheptatrienemolybdenum_tricarbonyl
• Mol file: 12125-77-8.mol

Synonyms:Cycloheptatriene molybdenum tricarbonyl;12125-77-8;(Cycloheptatriene)molybdenum tricarbonyl;Cycloheptatrienemolybdenumtricarbonyl;carbon monoxide;cyclohepta-1,3,5-triene;molybdenum;MFCD00004160;cycloheptatrienemolybdenum tricarbonyl;FT-0636759

Chemical Property of Cycloheptatriene molybdenum tricarbonyl

Chemical Property:

• Melting Point: 100-101 °C (dec.)(lit.)
• PSA: 0.00000
• LogP: 1.43470
• Sensitive.: Air Sensitive
• Water Solubility.: It is insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 273.952748
• Heavy Atom Count: 14
• Complexity: 112

Purity/Quality:

99.5% ^*data from raw suppliers

Cycloheptatriene molybdenum tricarbonyl, 99% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].C1C=CC=CC=C1.[Mo]

Technology Process of Cycloheptatriene molybdenum tricarbonyl

There total 26 articles about Cycloheptatriene molybdenum tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.7%

Cyclohepta-1,3,5-triene (544-25-2) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → (cycloheptatriene)tricarbonylchromium(0) (12125-72-3)

Guidance literature:

In not given; boiling;;

DOI:10.1016/S0022-328X(00)84713-0 DOI:10.1039/JR9580004559 DOI:10.1016/S0022-328X(00)80286-7 DOI:10.1039/JR9610003475

Reference yield: 80.0%

tricarbonyltrispyridinechromium(0) (27792-49-0,40250-96-2) + Cyclohepta-1,3,5-triene (544-25-2) → (cycloheptatriene)tricarbonylchromium(0) (12125-72-3) + pentacarbonyl(pyridine)chromium(0) (14740-77-3)

Guidance literature:

In diethyl ether; in the presence of ether;;

DOI:10.1016/S0022-328X(00)84713-0 DOI:10.1039/JR9580004559 DOI:10.1016/S0022-328X(00)80286-7 DOI:10.1039/JR9610003475

Reference yield: 41.0%

tricarbonyl(η-tropylium)chromium tetrafluoroborate → (cycloheptatriene)tricarbonylchromium(0) (12125-72-3)

Guidance literature:

With methyl magnesium iodide; In diethyl ether;

DOI:10.1039/J39670001057

upstream raw materials:

[Mo(C₇H₈)(CO)2]

Cyclohepta-1,3,5-triene

molybdenum hexacarbonyl

ethanol

Downstream raw materials:

fac-(CH₂CHCH₂CH₂PH₂)3molybdenum(CO)3

Cyclohepta-1,3,5-triene

Mo(CO)3(P(C₆H₁₁)3)2(C₂H₄)

Mo(η(6)-2,4,6-tri-tert-butyl-1,3,5-phosphabenzene)(tert-butylphosphaacetylene)(CO)2

Refernces

• 1、 Hoffmann, Florian,Fester, Gerrit W.,Wagler, Joerg. "The rotationally disordered crystal structure of tropylium bromide C 7H7+Br-". . p. 1137 - 1142. Retrieved 2011/01/07.
• 2、 Kunkely,Vogler. "Excited state properties of the (tropylium)molybdenum tricarbonyl cation". . p. 395 - 396. Retrieved 2007/10/03.