Dixanthogen

Base Information

• Chemical Name: Dixanthogen
• CAS No.: 502-55-6
• Molecular Formula: C6H10 O2 S4
• Molecular Weight: 242.408
• European Community (EC) Number: 207-944-4
• NSC Number: 402561
• UNII: RN4CQ46FDM
• DSSTox Substance ID: DTXSID2041672
• Nikkaji Number: J86.098K
• Wikipedia: Dixanthogen
• Wikidata: Q5284770
• NCI Thesaurus Code: C80602
• Metabolomics Workbench ID: 154497
• ChEMBL ID: CHEMBL331743
• Mol file: 502-55-6.mol

Synonyms:Auligen;Bexide;bisethylxanthogen;diethyl dithiobis(thionoformate);diexanthogen;dixanthogen;ethyl xanthogen disulfide;EXD;Herbisan;O,O-diethyl dithiobis(thioformate);O,O-diethyl dithiobisthioformate;Sulfasan

Chemical Property of Dixanthogen

Chemical Property:

• Melting Point: 28-32°
• Refractive Index: 1.5341 (estimate)
• Boiling Point: 295.7°Cat760mmHg
• Flash Point: 132.6°C
• PSA: 133.24000
• Density: 1.36g/cm³
• LogP: 3.01060
• Water Solubility.: 2.763mg/L(25 oC)
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 7
• Exact Mass: 241.95636425
• Heavy Atom Count: 12
• Complexity: 142

Purity/Quality:

99% ^*data from raw suppliers

O,O-DIETHYL DITHIOBIS-(THIOFORMATE) Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22
• Safety Statements: 24

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=S)SSC(=S)OCC
• Recent ClinicalTrials: Chinese Medicine Therapy on Menopausal Symptoms
• Uses: Insecticide formulations; herbicide.

Technology Process of Dixanthogen

There total 49 articles about Dixanthogen which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

potassium ethyl xanthogenate (140-89-6) → bis-ethoxythiocarbonyldisulfane (502-55-6)

Guidance literature:

With iodine; In methanol; at 20 ℃;

DOI:10.1021/acs.macromol.0c01697

Reference yield: 81.0%

O-ethyl S-[2-oxo-2-(p-tolyl)ethyl] carbonodithioate (91496-28-5) → bis-ethoxythiocarbonyldisulfane (502-55-6) + 1,4-bis(4-tolyl)butane-1,4-dione (13145-56-7)

Guidance literature:

In acetonitrile; for 15h; Irradiation; Inert atmosphere;

DOI:10.1021/jo201385b

Reference yield: 77.0%

carbon disulfide (75-15-0,12122-00-8) + ethanol (64-17-5) → bis-ethoxythiocarbonyldisulfane (502-55-6)

Guidance literature:

carbon disulfide; ethanol; With potassium hydroxide; In water; at 20 ℃;

With Aliquat 336; p-toluenesulfonyl chloride; In dichloromethane; water; at -5 - 20 ℃; for 2.5h;

DOI:10.1016/j.tetlet.2006.04.031

upstream raw materials:

carbon disulfide

ethanol

bis-ethoxythiocarbonyl-trisulfane

bis(ethoxythiocarbonyl) tetrasulfide

Downstream raw materials:

-bis-ethylxanthogenat

Diphenyl-bisaethoxythiocarbonylmercapto-methan

O-ethyl hydrogen dithiocarbonate

N,N-diphenylthiourea

Refernces

• 1、 Dag, Oemer,Yaman, Seniz Oezalp,Oenal, Ahmet M.,Isci, Huseyin. "Spectroelectrochemistry of potassium ethylxanthate, bis(ethylxanthato)nickel(II) and tetraethylammonium tris(ethylxanthato)-nickelate(II)". . p. 2819 - 2824. Retrieved 2001.
• 2、 Mazzolini, Jerome,Mokthari, Ilham,Briquel, Remi,Boyron, Olivier,Delolme, Frederic,Monteil, Vincent,Bertin, Denis,Gigmes, Didier,D'Agosto, Franck,Boisson, Christophe. "Thiol-end-functionalized polyethylenes". . p. 7495 - 7503. Retrieved 2010.
• 3、 Jiang, Shaohua,Li, Yibiao,Luo, Xianglin,Huang, Guoling,Shao, Yan,Li, Dongli,Li, Bin. "NH4I/EtOCS2K promoted synthesis of substituted benzils from diphenylacetylene derivatives". supporting information. p. 3249 - 3252. Retrieved 2018/07/21.