trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium

Base Information

• Chemical Name: trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium
• CAS No.: 1112460-26-0
• Molecular Formula: CF₃O₃S*C₃₇H₂₇O₄S
• Molecular Weight: 716.755
• Mol file: 1112460-26-0.mol

Synonyms:trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium

Chemical Property of trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium

There total 1 articles about trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

9,9-bis(4-hydroxyphenyl)fluorene (3236-71-3) + bis(4-hydroxyphenyl) sulfoxide (1774-34-1) + lithium trifluoromethanesulfonate (33454-82-9) → trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium (1112460-26-0)

Guidance literature:

9,9-bis(4-hydroxyphenyl)fluorene; bis(4-hydroxyphenyl) sulfoxide; With methanesulfonic acid; phosphorus pentoxide; at 15 ℃; for 2h; Inert atmosphere;

lithium trifluoromethanesulfonate; In water; 4-methyl-2-pentanone; for 2h;

Reference yield: 55.0%

trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium (1112460-26-0) + methyl iodide (74-88-4) → trifluoromethanesulfonate [9,9-bis(4-methoxyphenyl)-9H-fluorene-2-yl]bis(4-methoxyphenyl)sulfonium (1112460-28-2)

Guidance literature:

trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium; With potassium carbonate; In N,N-dimethyl-formamide; Inert atmosphere;

methyl iodide; In N,N-dimethyl-formamide; at 20 ℃;

Reference yield: 55.0%

trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium (1112460-26-0) + methanesulfonyl chloride (124-63-0) → trifluoromethanesulfonate [9,9-bis(4-methanesulfonyloxyphenyl)-9H-fluorene-2-yl]bis(4-methanesulfonyloxyphenyl)sulfonium

Guidance literature:

With triethylamine; In dichloromethane; N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;

upstream raw materials:

9,9-bis(4-hydroxyphenyl)fluorene

bis(4-hydroxyphenyl) sulfoxide

lithium trifluoromethanesulfonate

Downstream raw materials:

trifluoromethanesulfonate [9,9-bis(4-methoxyphenyl)-9H-fluorene-2-yl]bis(4-methoxyphenyl)sulfonium

trifluoromethanesulfonate [9,9-bis[4-(4-fluorobenzoyloxy)phenyl]-9H-fluorene-2-yl]bis[4-(4-fluorobenzoyloxy)phenyl]sulfonium

Refernces