9,9-Bis(4-hydroxyphenyl)fluorene

Base Information

• Chemical Name: 9,9-Bis(4-hydroxyphenyl)fluorene
• CAS No.: 3236-71-3
• Deprecated CAS: 26088-14-2,58560-83-1,546094-08-0,1278524-13-2,1541170-23-3,2115792-79-3,1278524-13-2,546094-08-0,58560-83-1
• Molecular Formula: C25H18O2
• Molecular Weight: 350.417
• Hs Code.: 38220000
• European Community (EC) Number: 406-950-6,624-416-2
• DSSTox Substance ID: DTXSID5037731
• Nikkaji Number: J111.264C
• Wikidata: Q29460410
• ChEMBL ID: CHEMBL434829
• Mol file: 3236-71-3.mol

Synonyms:9,9-bis(4-hydroxyphenyl)fluorene;fluorene-9-bisphenol

Chemical Property of 9,9-Bis(4-hydroxyphenyl)fluorene

Chemical Property:

• Appearance/Colour: white crystalline powder
• Vapor Pressure: 1.07E-11mmHg at 25°C
• Melting Point: 224-226 °C(lit.)
• Refractive Index: 1.71
• Boiling Point: 526.4 °C at 760 mmHg
• PKA: 9.58±0.30(Predicted)
• Flash Point: 241 °C
• PSA: 40.46000
• Density: 1.288 g/cm³
• LogP: 5.46090
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Insoluble in water
• XLogP3: 6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 350.130679813
• Heavy Atom Count: 27
• Complexity: 455

Purity/Quality:

99%, ^*data from raw suppliers

9,9-Bis(4-Hydroxyphenyl)Fluorene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi, N
• Hazard Codes: Xi,N
• Statements: 36/38-50/53-36/37/38
• Safety Statements: 26-37-60-61-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3C2(C4=CC=C(C=C4)O)C5=CC=C(C=C5)O
• Uses: It can be used the intermediate of organic synthesis. 9,9-Bis (4-Hydroxyphenyl) Fluorene is used in the production of polyarylene ethers and extensively used in the study of polymer electrolyte membranes with the potential for fuel cell application. 4,4'-(9-fluorenylidene)diphenol be used for the synthesis of novel poly (arylene ether). Bisphenol FL may be used as an analytical reference standard for the quantification of the analyte in: Human breast milk using gas chromatography-tandem mass spectrometry (GC-MS/MS). Wastewaters and surface water using gas chromatography-mass spectrometry (GC-MS).

Technology Process of 9,9-Bis(4-hydroxyphenyl)fluorene

There total 11 articles about 9,9-Bis(4-hydroxyphenyl)fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Fluorene-9,9-bisphenol dimethyl ether (117766-40-2) → 9,9-bis(4-hydroxyphenyl)fluorene (3236-71-3)

Guidance literature:

Fluorene-9,9-bisphenol dimethyl ether; With boron tribromide; In dichloromethane; at 20 ℃; for 48h;

at 20 ℃; for 4h; under 12 Torr; Further stages.;

DOI:10.1039/b008451o

Reference yield: 97.0%

9-fluorenone (486-25-9,952573-42-1) + phenol (108-95-2,27073-41-2) → 9,9-bis(4-hydroxyphenyl)fluorene (3236-71-3)

Guidance literature:

With hydrogenchloride; In Zinc chloride; water; isopropyl alcohol;

Reference yield: 97.0%

9-fluorenone (486-25-9,952573-42-1) + phenol (108-95-2,27073-41-2) → bis-(4-hydroxyphenyl)methane (620-92-8) + 9,9-bis(4-hydroxyphenyl)fluorene (3236-71-3)

Guidance literature:

With hydrogenchloride; In Zinc chloride; water; isopropyl alcohol;

upstream raw materials:

Fluorene-9,9-bisphenol dimethyl ether

9-fluorenone

phenol

methoxybenzene

Downstream raw materials:

9,9-bis(4-(2-hydroxyethoxy)phenyl)fluorene

Fluorene-9,9-bisphenol dimethyl ether

trifluoromethanesulfonate [9,9-bis(4-hydroxyphenyl)-9H-fluorene-2-yl]bis(4-hydroxyphenyl)sulfonium

4-(9-(4-(allyloxy)phenyl)-9H-fluorene-9-yl)phenol

Refernces

• 1、 -. "Preparation method of 9, 9-bis [(2, 3-epoxypropoxy) phenyl] fluorene". Paragraph 0034-0038. . Retrieved 2021/04/17.
• 2、 Bai, Wei,Gao, Zhanxian,Lu, Xinxin,Wei, Jialun,Yan, Lei,Yu, Limei. "Synthesis of 9,9-bis(4-hydroxyphenyl) fluorene catalyzed by bifunctional ionic liquids". . p. 32559 - 32564. Retrieved 2021/12/07.