[Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₅)]BF₄

Base Information

• Chemical Name: [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₅)]BF₄
• CAS No.: 916148-26-0
• Molecular Formula: BF₄*C₁₇H₃₁FeN₄S
• Molecular Weight: 466.178
• Mol file: 916148-26-0.mol

Synonyms:[Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₅)]BF₄

Chemical Property of [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₅)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₅)]BF₄

There total 2 articles about [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₅)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1,4,8,12-Tetraazacyclopentadecan (15439-16-4) + iron(II) tetrafluoroborate hexahydrate + sodium thiophenolate (930-69-8) → [Fe(II)(1,4,8,12-tetraazacyclopentadecane)(SC6H5)]BF4 (916148-26-0)

Guidance literature:

In methanol; byproducts: NaBF4; (N2 or Ar, Schlenk) to a soln. of Fe(BF4)2 in methanol was added a soln.of tetraamine-compound in methanol dropwise, stirred for 45 min, a meth anolic soln. of Na-thiolate was added, the mixt. was stirred overnight; methanol was removed under vac., ppt. was dissolved in CH2Cl2, filtered,vapor diffusion of diethyl ether for a week; elem. anal.;

DOI:10.1021/ja8031828

Reference yield:

1,4,8,12-Tetraazacyclopentadecan (15439-16-4) + iron(II) tetrafluoroborate + sodium thiophenolate (930-69-8) → [([15]aneN4)Fe(II)(SPh)]BF4 (916148-26-0)

Guidance literature:

In dichloromethane; byproducts: NaBF4;

DOI:10.1021/ja064525o

Reference yield:

di-(18)O-tert-butyl hydroperoxide (499106-72-8) + [([15]aneN4)Fe(II)(SPh)]BF4 (916148-26-0) → [Fe(II)([15]aneN4)(SC6H5)((18)O(18)O-t-Bu)]BF4 (916148-33-9)

Guidance literature:

In dichloromethane; complex, alkyl hydroperoxide, CH2Cl2, -78°C; not sepd., detected by spectra;

DOI:10.1021/ja064525o

upstream raw materials:

1,4,8,12-Tetraazacyclopentadecan

sodium thiophenolate

Downstream raw materials:

[Fe(II)([15]aneN₄)(SC₆H₅)(⁽¹⁸⁾O⁽¹⁸⁾O-t-Bu)]BF₄

[Fe(II)([15]aneN₄)(SC₆H₅)(OO-t-Bu)]BF₄

[Fe(II)([15]aneN₄)(SC₆H₅)(OO-cumenyl)]BF₄

[Fe(III)(1,4,8,12-tetraazacyclopentadecane)(SC₆H₅)(t-butylperoxo)]BF₄

Refernces

• 1、 Krishnamurthy, Divya,Kasper, Gary D.,Namuswe, Frances,Kerber, William D.,Sarjeant, Amy A. Narducci,Moenne-Loccoz, Pierre,Goldberg, David P.. "A low-spin alkylperoxo-iron(III) complex with weak Fe-O and O-O bonds: Implications for the mechanism of superoxide reductase". . p. 14222 - 14223. Retrieved 2008/02/09.