S-2-phenylbutyraldehyde

Base Information

• Chemical Name: S-2-phenylbutyraldehyde
• CAS No.: 106356-54-1
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.205
• Mol file: 106356-54-1.mol

Synonyms:S-2-phenylbutyraldehyde

Chemical Property of S-2-phenylbutyraldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-2-phenylbutyraldehyde

There total 20 articles about S-2-phenylbutyraldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

→ S-2-phenylbutyraldehyde (106356-54-1)

Guidance literature:

Reference yield: 22.0%

carbon monoxide (201230-82-2) + cis-1-phenyl-1-propylene (766-90-5) → 2-benzylpropionaldehyde (5445-77-2) + S-2-phenylbutyraldehyde (106356-54-1) + (S)-2-methylbutanal (42307-60-8)

Guidance literature:

With acetylacetonatodicarbonylrhodium(l); hydrogen; (R,S)-binaphos; In benzene; under 76000 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/ja970049d

Reference yield: 2.0%

1-propenylbenzene (873-66-5) + carbon monoxide (201230-82-2) → 2-benzylpropionaldehyde (5445-77-2) + S-2-phenylbutyraldehyde (106356-54-1) + (S)-2-methylbutanal (42307-60-8)

Guidance literature:

With acetylacetonatodicarbonylrhodium(l); hydrogen; (R,S)-binaphos; In benzene; under 76000 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/ja970049d

upstream raw materials:

1-propenylbenzene

carbon monoxide

trimethylaluminum

(2S-trans)-3-(Phenylmethyl)oxiranemethanol

Downstream raw materials:

(4R,5S)-5-phenyl-1-hepten-4-ol

(4S,5S)-5-phenyl-1-hepten-4-ol

(2R,3S)-1-nitro-3-phenylpentan-2-ol

(S)-2-phenylbutan-1-ol

Refernces

• 1、 Carrilho, Rui M.B.,Neves,Loureno, Mirtha A.O.,Abreu, Artur R.,Rosado, Mário T.S.,Abreu, Paulo E.,Eusébio, M. Ermelinda S.,Kollár, László,Bayón, J. Carles,Pereira, Mariette M.. "Rhodium/tris-binaphthyl chiral monophosphite complexes: Efficient catalysts for the hydroformylation of disubstituted aryl olefins". experimental part. p. 28 - 34. Retrieved 2012/02/04.
• 2、 Mitsui, Kazuhisa,Sato, Takayuki,Urabe, Hirokazu,Sato, Fumie. "Stereoselective Construction of Acyclic Carbon Chains by a One-Pot Coupling Process Based on Alkenyloxazoline-Titanium Complexes". . p. 490 - 492. Retrieved 2007/10/03.