N-(diethoxyphosphoryl)imidazolium ion

Base Information

• Chemical Name: N-(diethoxyphosphoryl)imidazolium ion
• CAS No.: 113947-93-6
• Molecular Formula: C₇H₁₄N₂O₃P
• Molecular Weight: 205.174
• Mol file: 113947-93-6.mol

Synonyms:N-(diethoxyphosphoryl)imidazolium ion

Chemical Property of N-(diethoxyphosphoryl)imidazolium ion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(diethoxyphosphoryl)imidazolium ion

There total 11 articles about N-(diethoxyphosphoryl)imidazolium ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1H-imidazole (288-32-4) + paraoxon (311-45-5) → diethyl phosphate (48042-47-3) + p-nitrophenolate (14609-74-6) + N-(diethoxyphosphoryl)imidazolium ion (113947-93-6)

Guidance literature:

In water; acetonitrile; at 25 ℃; pH=7.1; Kinetics;

DOI:10.1016/j.molcata.2015.03.020

Reference yield:

1H-imidazole (288-32-4) + diethyl (2-nitrophenyl) phosphate (4532-02-9) → 2-Nitrophenolate ion (16554-53-3) + N-(diethoxyphosphoryl)imidazolium ion (113947-93-6)

Guidance literature:

With buffer: tris(hydroxymethyl)aminomethane; In 1,4-dioxane; water; at 25 ℃; Equilibrium constant; pH 7.85, 0.5 M ionic strength;

DOI:10.1021/jo00245a015

Reference yield:

1H-imidazole (288-32-4) + p-cyanophenyl diethyl phosphate (6132-16-7) → 4-cyanophenolate (14609-76-8) + N-(diethoxyphosphoryl)imidazolium ion (113947-93-6)

Guidance literature:

With buffer; In 1,4-dioxane; water; at 25 ℃; Equilibrium constant; pH = 8.5, 0.5 M ionic strength;

DOI:10.1021/jo00245a015

upstream raw materials:

1H-imidazole

paraoxon

diethyl pentafluorophenyl phosphate

1-diethylphosphoryloxy-4-(1-oxoethyl)benzene

Downstream raw materials:

1H-imidazole

3-chlorophenyl diethyl phosphate

[1,1'-biphenyl]-4-yl diethyl phosphate

2-(chlorophenyl) diethylphosphate

Refernces

• 1、 Ba-Saif, Salem,Williams, Andrew. "Transfer of the Diethoxyphosphoryl Group between Imidazole and Aryloxy Anion Nucleophiles". . p. 2204 - 2209. Retrieved 2007/10/02.