4-cyanophenolate

Base Information

• Chemical Name: 4-cyanophenolate
• CAS No.: 14609-76-8
• Molecular Formula: C₇H₄NO
• Molecular Weight: 118.115
• Mol file: 14609-76-8.mol

Synonyms:4-cyanophenolate

Chemical Property of 4-cyanophenolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-cyanophenolate

There total 44 articles about 4-cyanophenolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

p-Cyanophenyl p-nitrobenzenesulphonate (128886-86-2) → 4-cyanophenolate (14609-76-8)

Guidance literature:

With sodium hydroxide; In water; dimethyl sulfoxide; acetonitrile; at 25 ℃; Kinetics;

DOI:10.1002/bkcs.10297

Reference yield:

4-cyanophenyl benzoate (16513-72-7) → 4-cyanophenolate (14609-76-8) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With hydroxide; In water; dimethyl sulfoxide; at 25 ℃; Kinetics; Alkaline hydrolysis;

DOI:10.1021/jo026339g

Reference yield:

p-nitrophenyl picolinate (74104-89-5) → 2-Picolinic acid (98-98-6) + 4-cyanophenolate (14609-76-8)

Guidance literature:

With sodium hydroxide; In water; acetonitrile; at 25 ℃; Kinetics; Mechanism;

DOI:10.1002/bkcs.10211

upstream raw materials:

1H-imidazole

p-cyanophenyl diethyl phosphate

triphenylmethyl 4-cyanophenyl ether

4-cyanophenoxyl radical

Downstream raw materials:

4-cyanophenyl acetate

3,4-dinitrophenoxide ion

p-nitrophenolate

4-cyanophenyl diphenylphosphinate

Refernces

• 1、 Um, Ik-Hwan,Park, Kyoung-Ho. "Kinetic Study on Nucleophilic Substitution Reactions of O-Phenyl O-Y-substituted-Phenyl Thionocarbonates with 1,8-Diazabicyclo[5.4.0]undec-7-ene in Acetonitrile". . p. 1169 - 1173. Retrieved 2017/09/13.
• 2、 Moon, Ji-Hyun,Kim, Min-Young,Han, So-Yeop,Um, Ik-Hwan. "Kinetic study on alkaline hydrolysis of Y-substituted phenyl X-substituted benzenesulfonates: Effects of changing nucleophile from azide to hydroxide ion on reactivity and transition-state structure". . p. 1563 - 1568. Retrieved 2015/08/11.