3,4-dinitrophenoxide ion

Base Information

• Chemical Name: 3,4-dinitrophenoxide ion
• CAS No.: 60154-37-2
• Molecular Formula: C₆H₃N₂O₅
• Molecular Weight: 183.1
• Mol file: 60154-37-2.mol

Synonyms:3,4-dinitrophenoxide ion

Chemical Property of 3,4-dinitrophenoxide ion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,4-dinitrophenoxide ion

There total 62 articles about 3,4-dinitrophenoxide ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4-dinitro-phenyl-acetate (10186-94-4) + 2-methylphenolate anion (20217-30-5) → 2-methylphenyl acetate (533-18-6) + 3,4-dinitrophenoxide ion (60154-37-2)

Guidance literature:

With potassium chloride; In water; at 25 ℃; Rate constant;

DOI:10.1021/ja00058a006

Reference yield:

3,4-dinitrophenyl benzoate (477881-01-9) → 3,4-dinitrophenoxide ion (60154-37-2) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With hydroxide; In water; dimethyl sulfoxide; at 25 ℃; Kinetics; Alkaline hydrolysis;

DOI:10.1021/jo026339g

Reference yield:

piperidine (110-89-4) + 3,4-dinitrophenyl benzoate (477881-01-9) → N-benzoylpiperidine (776-75-0) + 3,4-dinitrophenoxide ion (60154-37-2)

Guidance literature:

In water; dimethyl sulfoxide; at 25 ℃; Kinetics;

DOI:10.1021/jo0606958

upstream raw materials:

3,4-dinitro-phenyl-acetate

3-chlorophenoxide

phenolate

p-cresolate

Refernces

• 1、 Um, Ik-Hwan,Park, Kyoung-Ho. "Kinetic Study on Nucleophilic Substitution Reactions of O-Phenyl O-Y-substituted-Phenyl Thionocarbonates with 1,8-Diazabicyclo[5.4.0]undec-7-ene in Acetonitrile". . p. 1169 - 1173. Retrieved 2017/09/13.
• 2、 Crampton, Michael R.,Robotham, Ian A.. "Kinetics of the reaction of phenyl picrates with phenoxide ions in water. Concerted or stepwise?". . p. 1084 - 1089. Retrieved 2014/01/06.