N-allyl-N-methyl-O-benzoyl hydroxylamine

Base Information

• Chemical Name: N-allyl-N-methyl-O-benzoyl hydroxylamine
• CAS No.: 1286764-15-5
• Molecular Formula: C₁₁H₁₃NO₂
• Molecular Weight: 191.23
• Mol file: 1286764-15-5.mol

Synonyms:N-allyl-N-methyl-O-benzoyl hydroxylamine

Chemical Property of N-allyl-N-methyl-O-benzoyl hydroxylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of N-allyl-N-methyl-O-benzoyl hydroxylamine

There total 1 articles about N-allyl-N-methyl-O-benzoyl hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

N-methyl-N-allylamine (627-37-2) + dibenzoyl peroxide (94-36-0) → N-allyl-N-methyl-O-benzoyl hydroxylamine (1286764-15-5)

Guidance literature:

With dipotassium hydrogenphosphate; In N,N-dimethyl-formamide; at 25 ℃; for 6h; Inert atmosphere;

DOI:10.1002/anie.201710931

Reference yield: 89.0%

N-allyl-N-methyl-O-benzoyl hydroxylamine (1286764-15-5) + (4-methoxyphenyl)zinc pivalate → N-Allyl-N-methyl-4-methoxyaniline (150596-75-1)

Guidance literature:

With Li₂CoCl₄; In tetrahydrofuran; at 25 ℃; for 2h; Inert atmosphere;

DOI:10.1002/anie.201710931

Reference yield: 85.0%

N-allyl-N-methyl-O-benzoyl hydroxylamine (1286764-15-5) + phenyllithium (591-51-5) → N-allyl-N-methylaniline (6628-07-5)

Guidance literature:

phenyllithium; With 3-butyl-1,1-diethyl-1,3-dihydrobenzo[c][1,2]oxasilole; In tetrahydrofuran; dibutyl ether; at -78 - 20 ℃; Inert atmosphere;

N-allyl-N-methyl-O-benzoyl hydroxylamine; With copper(l) iodide; N-cyclohexyl-1-[2-(diphenylphosphanyl)phenyl]methanimine; In tetrahydrofuran; dibutyl ether; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol4023084

upstream raw materials:

N-methyl-N-allylamine

dibenzoyl peroxide

Downstream raw materials:

N-allyl-4-bromo-N-methylaniline

N-allyl-N-methylaniline

N-Allyl-N-methyl-4-methoxyaniline

Refernces

• 1、 Matsuda, Naoki,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro. "An annulative electrophilic amination approach to 3-aminobenzoheteroles". supporting information; experimental part. p. 617 - 625. Retrieved 2012/02/16.