Tris[2-phenylpyridinato-C2,N]iridium(III)

Base Information

• Chemical Name: Tris[2-phenylpyridinato-C2,N]iridium(III)
• CAS No.: 94928-86-6
• Molecular Formula: C33H27IrN3
• Molecular Weight: 654.794
• Hs Code.: 28439000
• European Community (EC) Number: 635-640-5,677-003-4
• Mol file: 94928-86-6.mol

Synonyms:94928-86-6;Tris[2-phenylpyridinato-C2,N]iridium(III);Ir(ppy)3;Tris(2-phenylpyridinato)iridium(III);Tris(2-phenylpyridinato)iridium(III) (purified by sublimation);tris(2-(pyridin-2-yl)phenyl)iridium;TRIS[2-(PYRIDIN-2-YL)PHENYL]IRIDIUM;MFCD12022527;fac-Tris(2-phenylpyridine)iridium(III);693794-98-8;SCHEMBL294298;BCP07959;AKOS005145796;AC-33754;SY047587;T1946;T3716;EN300-26209983;Tris[2-phenylpyridinato-C2,N]iridium(III), 98%;Tris[2-phenylpyridinato-C2,N]iridium(III), 99%;Tris[2-phenylpyridinato-C2,N]iridium(III), sublimed grade;Tris[2-phenylpyridinato-C2,N]iridium(III), purified by sublimation

Chemical Property of Tris[2-phenylpyridinato-C2,N]iridium(III)

Chemical Property:

• Melting Point: 328 °C
• PSA: 38.67000
• LogP: 7.64640
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 655.15995
• Heavy Atom Count: 37
• Complexity: 836

Purity/Quality:

99% ^*data from raw suppliers

Tris(2-phenylpyridinato)iridium(III) >98.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.[Ir+3]
• Description: Tris(2-phenylpyridine)iridium(III), Ir(ppy)3, is used widely in organic light-emitting diodes (OLEDs) due to its high quantum yields and thermal stability.
• Uses: suzuki reaction Tris(2-phenylpyridine)iridium can be useful as a photoredox catalyst in the preparation of fused-quinoxaline derivatives, difluorinated ketones and carbazoles. It can be a useful modifier in optogenetic control of behavior of larva expressing ChR2 in Drosophila melanogaster. It can also be useful in the development of a metal-?containing nucleoside that possesses both therapeutic and diagnostic activity against cancer.

Technology Process of Tris[2-phenylpyridinato-C2,N]iridium(III)

There total 12 articles about Tris[2-phenylpyridinato-C2,N]iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.1%

2-phenylpyridine (1008-89-5) + iridium(III) chloride → fac-Ir(ppy)3 (344426-19-3,693794-98-8,911406-78-5,94928-86-6,955950-26-2)

Guidance literature:

In water; at 205 ℃; for 48h; Temperature; Inert atmosphere;

Reference yield: 89.0%

2-phenylpyridine (1008-89-5) + iridium(III) chloride → fac-Ir(ppy)3 (344426-19-3,693794-98-8,911406-78-5,94928-86-6,955950-26-2)

Guidance literature:

With sodium carbonate; In water; at 200 ℃; for 48h; Product distribution / selectivity; Sealed autoclave;

Reference yield: 88.0%

2-phenylpyridine (1008-89-5) + [Ir2(ppy)4I2] → fac-Ir(ppy)3 (344426-19-3,693794-98-8,911406-78-5,94928-86-6,955950-26-2)

Guidance literature:

In water; at 200 ℃; for 24h; Sealed autoclave;

upstream raw materials:

2-phenylpyridine

1,2-diphenyl-1H-benzoimidazole

1-phenylisoquinoline

2,5-diphenyl-4-methylpyridine

Downstream raw materials:

[Ir(N,C'-NC₅H₄-2-C₆H₄-2)₃]⁽¹⁺⁾

Refernces

• 1、 -. "Preparation method of mer-Ir(ppy)3". Paragraph 0042-0043. . Retrieved 2021/11/14.
• 2、 -. "METHOD FOR THE SYNTHESIS AND ISOLATION OF FACIAL-TRIS-HOMOLEPTIC PHENYLPYRIDINATO IRIDIUM (III) PHOTOCATALYSTS". Paragraph 0114-0127; 0128-0132; 0133-0136. . Retrieved 2018/09/28.