Sucrose benzoate

Base Information

• Chemical Name: Sucrose benzoate
• CAS No.: 12738-64-6
• Molecular Formula: C₁₀H₁₁FeN
• Molecular Weight: 201.051
• Hs Code.: 29400090
• Mol file: 12738-64-6.mol

Synonyms:S-(-)-Tert-butylamino-1,2-propanediol;S(-)-tert-butylamino-1,2-propanediol;α-d-Glucopyranoside, β-d-fructofuranosyl, benzoate;beta-D-Fructofuranosyl-alpha-D-glucopyranoside benzoate;

Chemical Property of Sucrose benzoate

Chemical Property:

• Appearance/Colour: COA
• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 93-100oC
• Refractive Index: 1.657
• Boiling Point: 742.524°C at 760 mmHg
• Flash Point: 261.51°C
• PSA: 52.49000
• Density: 1.42g/cm3
• LogP: 0.11860
• Solubility.: aromatics, ketones and esters: soluble
• Water Solubility.: 3mg/L at 20℃

Purity/Quality:

99% ^*data from raw suppliers

Sucrose octabenzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Sucrose benzoate

There total 57 articles about Sucrose benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

azoferrocene → aminoferrocene (1273-82-1)

Guidance literature:

With hydrogenchloride; zinc; In ethanol; water; benzene;

Reference yield: 99.0%

N-ferrocenyl phthalimide (1294-21-9) → aminoferrocene (1273-82-1)

Guidance literature:

With hydrazine hydrate; In ethanol; for 2h; Reflux; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c9dt03808f

Reference yield: 99.0%

N-ferrocenyl phthalimide (1294-21-9) + hydrazine hydrate (7803-57-8,79785-97-0) → aminoferrocene (1273-82-1)

Guidance literature:

In ethanol; Ar, hydrazine added to a soln. of Fe compd., refluxed for 2 h; cooled to ambient temp., water added, extd. (diethyl ether), extract dried (Na2SO4), evapd. (vac.) to dryness; elem. anal.;

DOI:10.1002/ejic.200300897

upstream raw materials:

lithium aluminium tetrahydride

O-Methylhydroxylamin

lithiumferrocene

N-benzyloxyamine

Refernces

• 1、 Boeser, Lisa,Christmann, Mathias,Hartmayer, Bence,Heretsch, Philipp,Kleoff, Merlin,Sarkar, Biprajit,Schwan, Johannes. "Scalable Synthesis of Functionalized Ferrocenyl Azides and Amines Enabled by Flow Chemistry". supporting information. . Retrieved 2020/02/04.
• 2、 Carter, Cole,Kratish, Yosi,Jurca, Titel,Gao, Yanshan,Marks, Tobin J.. "Bis-ferrocenyl-pyridinediimine trinuclear mixed-valent complexes with metal-binding dependent electronic coupling: Synthesis, structures, and redox-spectroscopic characterization". . p. 18715 - 18729. Retrieved 2020/11/17.