Lithium, ferrocenyl-(8CI,9CI)

Base Information

• Chemical Name: Lithium, ferrocenyl-(8CI,9CI)
• CAS No.: 1271-15-4
• Molecular Formula: C10H9 Fe Li
• Molecular Weight: 191.969
• Mol file: 1271-15-4.mol

Synonyms:Iron,dicyclopentadienyl-, lithium deriv. (6CI,7CI); Ferrocene, lithium complex;1-Ferrocenyllithium; Ferrocene, lithio-; Ferrocenyllithium; Lithioferrocene

Chemical Property of Lithium, ferrocenyl-(8CI,9CI)

Chemical Property:

• PSA: 0.00000
• LogP: 0.74140

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Lithium, ferrocenyl-(8CI,9CI)

There total 22 articles about Lithium, ferrocenyl-(8CI,9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

bromoferrocene (1273-73-0) → lithiumferrocene (1271-15-4)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; under N2, CpFeC5H4Br in Et2O treated at -78°C with equiv. amt. of n-BuLi in hexane (1.6 M), stirred at 0°C; ppt. sepd. by decantation, dried in high vac.;

DOI:10.1016/0022-328X(87)87165-6

Reference yield: 90.0%

1-(chloromercuri)ferrocene + ethyllithium (811-49-4) → lithiumferrocene (1271-15-4)

Guidance literature:

In diethyl ether; byproducts: Hg(C2H5)2; room temp.;

Reference yield: 87.0%

n-butyllithium (109-72-8,29786-93-4) + bromoferrocene (1273-73-0) → lithiumferrocene (1271-15-4)

Guidance literature:

In diethyl ether; hexane; molar ratio fc-Br:LiC4H9-n = 1:2.2, room temp.;

DOI:10.1016/S0022-328X(00)93496-X

upstream raw materials:

ferrocene

n-butyllithium

sec.-butyllithium

bis(ferrocenyl)mercury

Downstream raw materials:

(TPP)Ge(C₆H₅)(Fc)

benzoylferrocene

Refernces

• 1、 Malessa, Maik,Heck, Juergen,Kopf, Juergen,Garcia, M. Helena. "Polar cofacially fixed sandwich complexes: Do they demonstrate second harmonic generation (SHG)?". . p. 857 - 867. Retrieved 2006.
• 2、 Bloemker, Tobias,Boeckmann, Philipp,Kehr, Gerald,Froehlich, Roland,Erker, Gerhard. "Synthesis and reactions of ferrocenyl-capped long-chain alkynes". . p. 587 - 594. Retrieved 2009.
• 3、 Hedberg,Rosenberg. "". . p. 4011. Retrieved 1969.
• 4、 Pannell,Wang,Sharma,Cervantes-Lee. "Bis(ferrocenylsilyl)thiophenes and ferrocenylene(silylene) thiophene oligomers". . p. 291 - 295. Retrieved 2000.
• 5、 Nikkonen, Taru,Moreno Oliva, Mara,Taubert, Stefan,Melchionna, Michele,Kahnt, Axel,Helaja, Juho. "Synthesis, Aromaticity and Photophysical Behaviour of Ferrocene- and Ruthenocene-Appended Semisynthetic Chlorin Derivatives". . p. 12755 - 12768. Retrieved 2015.
• 6、 Herberhold, Max,Kniesel, Heidemarie. "Untersuchungen zur Darstellung und Reaktivitaet von Triferrocenylwolfram(VI)-Komplexen". . p. 205 - 218. Retrieved 1989.
• 7、 Kaufmann, Sebastian,Radius, Michael,Moos, Eric,Breher, Frank,Roesky, Peter W.. "Rhodium(I) and Iridium(I) Complexes of Ferrocenyl-Functionalized Amidinates and Bis(amidinates): κ2 N-Coordination Versus Ferrocenyl Ortho-Metalation". . p. 1721 - 1732. Retrieved 2019.
• 8、 Clavero, Pau,Grabulosa, Arnald,Rocamora, Mercè,Muller, Guillermo,Font-Bardia, Mercè. "Ruthenium complexes of: P -stereogenic phosphines with a heterocyclic substituent". . p. 8513 - 8531. Retrieved 2016.