Cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)mercury;iron(2+)

Base Information

• Chemical Name: Cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)mercury;iron(2+)
• CAS No.: 1274-09-5
• Molecular Formula: C₂₀H₁₈Fe₂Hg
• Molecular Weight: 570.647
• Mol file: 1274-09-5.mol

Synonyms:

Chemical Property of Cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)mercury;iron(2+)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 571.981365
• Heavy Atom Count: 23
• Complexity: 204

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [CH-]1C=CC=C1.[CH-]1C=CC=C1.C1=C[C-](C=C1)[Hg][C-]2C=CC=C2.[Fe+2].[Fe+2]

Technology Process of Cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)mercury;iron(2+)

There total 6 articles about Cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)mercury;iron(2+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-(chloromercuri)ferrocene + pentaphenylantimony (2170-05-0) → bis(ferrocenyl)mercury (1274-09-5) + tetraphenylchloroantimony(V) (16894-68-1) + diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

In toluene; a mixt. of Sb-contg. and Hg-contg. compds. in toluene was heated at 100°C for 1 h; the react. mixt. was cooled; the residue was extd. with hot water; the ext. was evapd. to obtain Ph4SbCl; the water-insol. residue was chromd. on Silica gel L 5/40 (eluent petroleum ether) to obtain Ph2Hg; FeHg-contg. compd. insol. in petroleum ether was crystd. from toluene;

DOI:10.1023/B:RUGC.0000007667.67067.5a

Reference yield: 92.0%

1-(chloromercuri)ferrocene + pentaphenylantimony (2170-05-0) → bis(ferrocenyl)mercury (1274-09-5) + tetraphenylchloroantimony(V) (16894-68-1) + diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

In toluene; mixt. of ferrocenylmercury chloride and pentaphenylantimony in toluene heated at 90°C for 1 h in evacuated glass ampoule; crystals of Sb(C6H5)4Cl filtered off, removal of solvent from filtrate, chromy. (silica gel L 5/40, petroleum ether) yields Hg(C6H5)2, the residue insoluble in petroleum ether, diferrocenylmercury, was recrystd. fromtoluene;

DOI:10.1023/A:1024731719528

Reference yield:

1-(chloromercuri)ferrocene + pentacarbonylrhenium(1-) (14971-38-1,35725-77-0) → rhenium(I) pentacarbonyl chloride (14099-01-5) + bis(ferrocenyl)mercury (1274-09-5) + mercury

Guidance literature:

In tetrahydrofuran;

DOI:10.1039/J19660001602

upstream raw materials:

pentaphenylantimony

pentaphenylantimony

n-butyllithium

pentacarbonylrhenium^(1-)

Downstream raw materials:

ferrocene

lithiumferrocene

benzoylferrocene

chloroferrocene

Refernces

• 1、 Sharutin,Sharutina,Senchurin,Egorova,Ivanenko,Petrov. "Phenylation of Organic Derivatives of Mercury, Silicon, Tin, and Bismuth with Pentaphenylantimony and Pentaphenylphosphorus". . p. 202 - 203. Retrieved 2003.