Benzyl 2-naphthyl ether

Base Information

• Chemical Name: Benzyl 2-naphthyl ether
• CAS No.: 613-62-7
• Molecular Formula: C17H14O
• Molecular Weight: 234.298
• Hs Code.: 29093090
• European Community (EC) Number: 405-490-3
• UNII: TT5AWE5U2C
• DSSTox Substance ID: DTXSID80210201
• Nikkaji Number: J42.291F
• Wikidata: Q55525242
• ChEMBL ID: CHEMBL146439
• Mol file: 613-62-7.mol

Synonyms:benzyl 2-naphthyl ether

Chemical Property of Benzyl 2-naphthyl ether

Chemical Property:

• Appearance/Colour: COA
• Vapor Pressure: 7.02E-06mmHg at 25°C
• Melting Point: 96-98 °C
• Refractive Index: 1.642
• Boiling Point: 388.1 °C at 760 mmHg
• Flash Point: 156.4 °C
• PSA: 9.23000
• Density: 1.125 g/cm³
• LogP: 4.41880
• Solubility.: 5173.1 in mg/100g standard fat at 20 ℃
• Water Solubility.: 76-78μg/L at 20℃
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 234.104465066
• Heavy Atom Count: 18
• Complexity: 244

Purity/Quality:

99% ^*data from raw suppliers

Benzyl 2-Naphthyl Ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R53:May cause long-term adverse effects in the aquatic environment.
• Hazard Codes: R53:May cause long-term adverse effects in the aquatic environment.
• Statements: 53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)COC2=CC3=CC=CC=C3C=C2

Technology Process of Benzyl 2-naphthyl ether

There total 43 articles about Benzyl 2-naphthyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

naphthalen-2-yl acetate (1523-11-1) + benzyl bromide (100-39-0) → 2-benzyloxynaphthalene (613-62-7)

Guidance literature:

With sodium methylate; In N,N-dimethyl-formamide; for 0.5h; Ambient temperature;

DOI:10.1055/s-1997-3267

Reference yield: 97.0%

sodium 2-naphtholate (875-83-2) + benzyl chloride (100-44-7) → 2-benzyloxynaphthalene (613-62-7)

Guidance literature:

In various solvent(s); at 110 ℃; for 24h;

DOI:10.1016/S0040-4039(00)60103-X

Reference yield: 97.0%

2-(dimethyl-1,1’-dimethylethylsilyloxy)naphthalene (62790-91-4) + benzyl bromide (100-39-0) → 2-benzyloxynaphthalene (613-62-7)

Guidance literature:

With cesium fluoride; In N,N-dimethyl-formamide; for 12h; Ambient temperature;

DOI:10.1055/s-1997-3267

upstream raw materials:

phenyldiazomethane

β-naphthol

benzyl bromide

sodium 2-naphtholate

Downstream raw materials:

2-Benzyloxy-1-chloronaphthalin

(2-naphthyl)phenylmethanol

toluene

β-naphthol

Refernces

• 1、 Yabuta, Tatsushi,Hayashi, Masahiko,Matsubara, Ryosuke. "Photocatalytic Reductive C-O Bond Cleavage of Alkyl Aryl Ethers by Using Carbazole Catalysts with Cesium Carbonate". . p. 2545 - 2555. Retrieved 2021/02/01.
• 2、 Liu, Long,Tang, Yuanyuan,Wang, Kunyu,Huang, Tianzeng,Chen, Tieqiao. "Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bond Formation via C-N Cleavage of Benzyl Ammonium Salts". . p. 4159 - 4170. Retrieved 2021/03/09.