Nickel diisobutyldithiocarbamate

Base Information

• Chemical Name: Nickel diisobutyldithiocarbamate
• CAS No.: 15317-78-9
• Molecular Formula: C18H36N2NiS4
• Molecular Weight: 467.451
• Hs Code.: 2930909090
• Mol file: 15317-78-9.mol

Synonyms:Isobutyl niclate;Nickel diisobutyldithiocarbamate;N,N-bis(2-methylpropyl)carbamodithioate;nickel(2+);Nickel, bis[bis(2-methylpropyl)carbamodithioato-S,S']-, (SP-4-1)-;N,N-bis(2-methylpropyl)carbamodithioate,nickel(2+);Nickel diisobutyldithiocarbamate.;AKOS015913866;Bis({[bis(2-methylpropyl)carbamothioyl]sulfanyl})nickel

Chemical Property of Nickel diisobutyldithiocarbamate

Chemical Property:

• Appearance/Colour: COA
• Vapor Pressure: 0.0262mmHg at 25°C
• Melting Point: 173-181oC
• Boiling Point: 247.1 °C at 760 mmHg
• Flash Point: 103.2 °C
• PSA: 121.26000
• Density: 1.27 Mg/m3 at 25oC (77°F)
• LogP: 6.16560
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 466.111476
• Heavy Atom Count: 25
• Complexity: 307

Purity/Quality:

99% ^*data from raw suppliers

Bis({[bis(2-methylpropyl)carbamothioyl]sulfanyl})nickel 96% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)CN(CC(C)C)C(=S)[S-].CC(C)CN(CC(C)C)C(=S)[S-].[Ni+2]

Technology Process of Nickel diisobutyldithiocarbamate

There total 3 articles about Nickel diisobutyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

nickel(II) chloride hexahydrate + sodium diisobutyldithiocarbamate monohydrate → bis(N,N-diisobutyldithiocarbamato-S,S')nickel(II) (15317-78-9)

Guidance literature:

In water; ligand in H2O added to Ni salt in H2O under stirring; decanted, filtered, dried (air), recrystd.(EtOH/CHCl3 1:1), elem. anal.;

DOI:10.1007/s11173-005-0157-4

Reference yield:

Ni(((CH3)2CHCH2)2NCS2)3(1+)*Br(1-) = [Ni(((CH3)2CHCH2)2NCS2)3]Br (83202-05-5) → bis(N,N-diisobutyldithiocarbamato-S,S')nickel(II) (15317-78-9)

Guidance literature:

In chloroform; byproducts: Ni(2+), (i-Bu2NCS2)2; Irradiation (UV/VIS); irradiated (poly- (425-670 nm) and mono- (436 nm) chromatically); photometry; Kinetics;

Reference yield:

nickel(II) (14701-22-5) + diisobutylcarbodithioic acid sodium salt (2219-18-3) → bis(N,N-diisobutyldithiocarbamato-S,S')nickel(II) (15317-78-9)

Guidance literature:

In water; recrystn. from benzene;

upstream raw materials:

nickel(II)

diisobutylcarbodithioic acid sodium salt

Ni(((CH₃)2CHCH₂)2NCS₂)3⁽¹⁺⁾*Br^(1-) = [Ni(((CH₃)2CHCH₂)2NCS₂)3]Br

Refernces