sodium diisobutyldithiocarbamate

Base Information

• Chemical Name: sodium diisobutyldithiocarbamate
• CAS No.: 2219-18-3
• Molecular Formula: C9H19 N S2 . Na
• Molecular Weight: 227.37
• Hs Code.: 2930909090
• Mol file: 2219-18-3.mol

Synonyms:Carbamicacid, diisobutyldithio-, sodium salt (7CI,8CI); Carbamodithioic acid,bis(2-methylpropyl)-, sodium salt (9CI); N,N-Diisobutyldithiocarbamic acid,sodium salt; Sodium N,N-di(isobutyl)dithiocarbamate; Sodiumdiisobutyldithiocarbamate

Chemical Property of sodium diisobutyldithiocarbamate

Chemical Property:

• Vapor Pressure: 0.0262mmHg at 25°C
• Boiling Point: 247.1°Cat760mmHg
• Flash Point: 103.2°C
• PSA: 35.33000
• Density: g/cm³
• LogP: 2.43220

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium diisobutyldithiocarbamate

There total 2 articles about sodium diisobutyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

carbon disulfide (75-15-0,12122-00-8) + diisobutylamine (110-96-3) → diisobutylcarbodithioic acid sodium salt (2219-18-3)

Guidance literature:

diisobutylamine; With sodium hydroxide; In methanol; water; at 0 ℃; for 0.333333h;

carbon disulfide; In methanol; water; at 20 ℃;

DOI:10.1039/c2cc16395k

Reference yield:

diisobutylamine (110-96-3) + thioformaldehyde S-methylide (197161-24-3,53283-20-8,119052-11-8) → diisobutylcarbodithioic acid sodium salt (2219-18-3)

Guidance literature:

Alkaline conditions;

DOI:10.1016/j.ica.2011.01.006

Reference yield: 90.2%

diisobutylcarbodithioic acid sodium salt (2219-18-3) + N-phenylbenzohydrazonoyl chloride (15424-14-3) → C22H29N3S2 (78741-96-5)

Guidance literature:

In methanol; for 0.0833333h; heating on a steam bath;

upstream raw materials:

carbon disulfide

diisobutylamine

thioformaldehyde S-methylide

Downstream raw materials:

C₂₂H₂₉N₃S₂

methylene bis-(di-isobutylamino-dithioformate)

bis(di-isobutyldithiocarbamate)cadmium(II)

bis(N,N-diisobutyldithiocarbamato-S,S')nickel(II)

Refernces

• 1、 Ivanov,Ivakhnenko,Forsling,Gerasimenko. "Single-Crystal X-ray Diffraction and CP/MAS 13C and 15N NMR Study of Zinc N,N-Di-iso-butyldithiocarbamate Complex: A Unique Structural Organization". . p. 162 - 167. Retrieved 2003.
• 2、 Novikova,Ivanov,Egorova,Troshina,Rodionova,Smolentsev,Antzutkin. "Principles of the Construction of Polymer Structures, Heteronuclear (13C, 15N) CP-MAS NMR, and Thermal Behavior of Heteroleptic Bismuth(III) Complexes of the General Composition [Bi(S2CNR2)2X] (X = NO3, Cl)". . p. 695 - 705. Retrieved 2019.
• 3、 Bai, Zhongjie,Zhang, Jinlong,Zhang, Qiuping,Zhang, Taofeng,Li, Jili,Zhao, Quanyi,Wang, Zhen,He, Dian,Cheng, Jie,Zhang, Jingke,Liu, Bin. "Synthesis, toxicities and bio-activities of manganese complexes with CO and H2S dual donors". . p. 339 - 356. Retrieved 2018/10/20.
• 4、 -. "A disulphide diisobutylcarbamoylmethyl thiuram method for the preparation of (by machine translation)". Paragraph 0003; 0031. . Retrieved 2016/11/21.