Tetrapropylammonium hydroxide

Base Information

• Chemical Name: Tetrapropylammonium hydroxide
• CAS No.: 4499-86-9
• Deprecated CAS: 66082-78-8
• Molecular Formula: C12H29NO
• Molecular Weight: 203.368
• Hs Code.: 2923 90 00
• European Community (EC) Number: 224-800-6
• UNII: T686LUY7NK
• DSSTox Substance ID: DTXSID7052107
• Wikidata: Q27289727
• Mol file: 4499-86-9.mol

Synonyms:Tetrapropylammonium hydroxide;4499-86-9;Tetra-n-propylammonium hydroxide;Tetrapropyl ammonium hydroxide;TPAOH;Tetrapropylammonium oxide;Fluka 88110;1-Propanaminium, N,N,N-tripropyl-, hydroxide;tetrapropylazanium hydroxide;tetrapropylazanium;hydroxide;AMMONIUM, TETRAPROPYL-, HYDROXIDE;EINECS 224-800-6;UNII-T686LUY7NK;T686LUY7NK;N,N,N-Tripropyl-1-propanaminium hydroxide;AI3-24161;1-Propanaminium, N,N,N-tripropyl-, hydroxide (1:1);Tetrapropylammonium hydroxide 1.0M in Water;EC 224-800-6;Tetrapropylammonium hydroxide,40% w/w in water;MFCD00009360;Tetrapropylammoniumhydroxide;C12H29NO;Tetrapropylammonium bydroxide;SCHEMBL49582;C12H28N.HO;DTXSID7052107;HY-Y0407A;Tetrapropylammonium Hydroxide (TPAH);Tetrapropylammonium hydroxide solution;AKOS015907892;CS-15661;LS-19073;CS-0015126;CS-0201218;FT-0635328;I1130;T0171;T0964;T1020;T1565;F16346;A826700;W-106169;Q27289727;Tetrapropylammonium Hydroxide (10% in Water) [Reagent for Ion-Pair Chromatography]

Chemical Property of Tetrapropylammonium hydroxide

Chemical Property:

• Appearance/Colour: clear colourless solution
• Refractive Index: n20/D 1.370
• Boiling Point: 100-102 °C
• Flash Point: 102°C
• PSA: 23.06000
• Density: 1.00 g/mL at 20 °C
• LogP: 3.26640
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Solubility.: Miscible with strong electrolytes.
• Water Solubility.: Miscible in water
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 8
• Exact Mass: 203.224914549
• Heavy Atom Count: 14
• Complexity: 80.2

Purity/Quality:

99% ^*data from raw suppliers

Tetrapropylammonium Hydroxide (20-25% in Water) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Quaternary Amines
• Canonical SMILES: CCC[N+](CCC)(CCC)CCC.[OH-]
• Uses: Tetra-n-propylammonium hydroxide is used as an intermediate, ion exchange agent, surface-active agent and solvent. Further, it is used as an antistatic agent, detergent sanitizers, softener for textiles and paper products, emulsifying agents and pigment dispersers. It finds application as curing accelerators. In addition to this, it acts as a phase transfer catalyst in organic synthesis to enhance the reaction rate.

Technology Process of Tetrapropylammonium hydroxide

There total 1 articles about Tetrapropylammonium hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

tetra-n-propylammonium bromide (1941-30-6) → tetrapropylammonium hydroxide (4499-86-9)

Guidance literature:

With potassium hydroxide; In dichloromethane; at 20 ℃; for 10h;

DOI:10.1021/jp108003x DOI:10.1021/jp3015386

Reference yield: 99.7%

rhodium(III) chloride hydrate + tetrapropylammonium hydroxide (4499-86-9) → tetrapropylammonium perruthennate (114615-82-6)

Guidance literature:

rhodium(III) chloride hydrate; With sodium bromate; sodium carbonate; In water; at 30 - 40 ℃; for 5h;

tetrapropylammonium hydroxide; at 30 ℃; for 5h; Temperature;

Reference yield: 90.0%

RhI(tetraphenylporphyrin) (69509-35-9) + tetrapropylammonium hydroxide (4499-86-9) → [Rh(5,10,15,20-tetraphenylporphyrinato)(n-propyl)] (106161-22-2)

Guidance literature:

With air; In water; benzene; at 120 ℃; for 2h; Sealed tube;

DOI:10.1021/om500438s

upstream raw materials:

tetra-n-propylammonium bromide

Downstream raw materials:

tetrapropylammonium 4-[¹⁸F]fluorobenzoate

Tetrapropylammonium tetrafluoroborate

tri-n-propylamine

propene

Refernces

• 1、 Kavitha,Attri, Pankaj,Venkatesu, Pannuru,Devi, R. S. Rama,Hofman. "Influence of alkyl chain length and temperature on thermophysical properties of ammonium-based ionic liquids with molecular solvent". experimental part. p. 4561 - 4574. Retrieved 2012/07/02.