Chlororuthenium(1+);cyclopenta-1,3-diene;triphenylphosphane

Base Information

• Chemical Name: Chlororuthenium(1+);cyclopenta-1,3-diene;triphenylphosphane
• CAS No.: 32993-05-8
• Molecular Formula: C41H35ClP2Ru
• Molecular Weight: 726.199
• Hs Code.: 28439000
• European Community (EC) Number: 626-016-3
• Mol file: 32993-05-8.mol

Synonyms:Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II);32993-05-8;chlororuthenium(1+);cyclopenta-1,3-diene;triphenylphosphane

Chemical Property of Chlororuthenium(1+);cyclopenta-1,3-diene;triphenylphosphane

Chemical Property:

• Appearance/Colour: Orange powder
• Melting Point: 135 ºC
• PSA: 27.18000
• LogP: 8.60060
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 726.094593
• Heavy Atom Count: 45
• Complexity: 248

Purity/Quality:

≥98.0%,Ru≥13.9% ^*data from raw suppliers

Cyclopentadienylbis(triphenylphosphine)rutheniumChloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-37/39-36/37/39-22

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH-]1C=CC=C1.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru+]
• Uses: Cyclopentadienylbis(triphenylphosphine)ruthenium Chloride is used as an efficient transfer hydrogenation catalyst. It is used in the formation of indoles, isoquinolines and quinolines.

Technology Process of Chlororuthenium(1+);cyclopenta-1,3-diene;triphenylphosphane

There total 38 articles about Chlororuthenium(1+);cyclopenta-1,3-diene;triphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[(η5-C5H5)Ru(P(C6H5)2(2-CH3-C6H4))2Cl] (252894-17-0) + triphenylphosphine (603-35-0) → chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8)

Guidance literature:

In benzene-d6; a soln. in C6D6 was treated with twofold molar amount of PPh3 at 50°C (Ar);

DOI:10.1016/S0022-328X(00)00675-6

Reference yield: 92.0%

hydrogenchloride (7647-01-0,15364-23-5) + [(C5H5)Ru(P(C6H5)3)2(O2CC(C6H9)CHC(O)OCH3)] (910567-05-4) → chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8)

Guidance literature:

In chloroform-d1; N2, stirred at room temp. for ca. 4 h with aq. HCl; solvent removed (vac.), washed (diethyl ether);

DOI:10.1002/ejic.200500621

Reference yield: 90.0%

ruthenium trichloride hydrate (14898-67-0) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) + triphenylphosphine (603-35-0) → chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8)

Guidance literature:

In ethanol; byproducts: HCl; RuCl3 soln. added to refluxing soln. of PPh3, addn. of freshly destilled cyclopentadiene, mixt. refluxed for 60 min; suspension filtered, washed with ethanol and water, dried in vacuo;

upstream raw materials:

ruthenium trichloride hydrate

cyclopenta-1,3-diene

triphenylphosphine

ruthenium trichloride hydrate

Downstream raw materials:

[(η5-cyclopentadienyl)Ru(PPh3)2Br]

[Ru(η5-Cp)(triphenylphosphine)2(CN)]

Refernces

• 1、 Wilczewski, Tadeusz. "Cyclopentadienyl-ruthenium and -osmium complexes VII. Formation and properties of ion-pairs containing the dihydride (η-cyclopentadienyl)bis(triphenylphosphine)-ruthenium(IV) cation". . p. 219 - 230. Retrieved 1989.
• 2、 Bruce, Michael I.,Humphrey, Mark G.,Liddell, Michael J.. "Reactions of Transition Metal ?-Acetylides VIII. Preparation and Properties of some Aryldiazo-vinylidene Complexes". . p. 91 - 102. Retrieved 1987.
• 3、 Gorbachuk, Elena V.,Badeeva, Elena K.,Zinnatullin, Ruzal G.,Pavlov, Pavel O.,Dobrynin, Alexey B.,Gubaidullin, Aidar T.,Ziganshin, Marat A.,Gerasimov, Alexander V.,Sinyashin, Oleg G.,Yakhvarov, Dmitry G.. "Polymorphism and thermodynamic properties of chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II) complex". . p. 49 - 53. Retrieved 2016.
• 4、 Hill, David,Delaney, Connor,Clark, Miles,Eaton, Mathew,Hassan, Bakar,Hendricks, Olivia,Dang, Duy Khoi,Kirss, Rein U.. "Kinetics of phosphine substitution in CpRu(PPh3)2X (X = Cl, Br, I, N3, and NCO)". . p. 34425 - 34434. Retrieved 2017.
• 5、 Hall, Lewis M.,Milner, Lucy M.,Hart, Sam J.,Whitwood, Adrian C.,Lynam, Jason M.,Slattery, John M.. "Solvent- A nd anion-dependent rearrangement of fluorinated carbene ligands provides access to fluorinated alkenes". supporting information. p. 17655 - 17659. Retrieved 2019/12/23.