IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2

Base Information

• Chemical Name: IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2
• CAS No.: 100896-61-5
• Molecular Formula: C₅₈H₅₀Cl₂IrO₆P₄Rh
• Molecular Weight: 1332.96
• Mol file: 100896-61-5.mol

Synonyms:IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2

Chemical Property of IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2

There total 1 articles about IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

IrRhCl(CO)3(((C6H5)2P)2CH2)2 (87482-56-2) + dimethyl acetylenedicarboxylate (762-42-5) → IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2 (100896-61-5) + IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2*0.5CH2Cl2 (100815-11-0)

Guidance literature:

With carbon monoxide; In dichloromethane; excess of ligand was added to complex in CO-satd. CH2Cl2, mixt. was stirred for 1 h under CO; filtn. through diatomaceous earth, addn. of hexane, filtn., recrystallization from CH2Cl2-Et2O; elem. anal.; presence of other isomer is confirmed by IR and NMR;

DOI:10.1021/om00136a014

Reference yield: 80.0%

IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2 (100896-61-5) + IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2*0.5CH2Cl2 (100815-11-0) + silver perchlorate → IrCl(CO)Rh(CO)2(CH3CO2C2CO2CH3)(((C6H5)2P)2CH2)2(1+)*ClO4(1-)*0.5CH2Cl2 (100815-14-3)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; dichloromethane; addn. of AgClO4 to susp. of complex, stirring for 0.5 h under slow stream of CO; filtn. through diatomaceous earth under CO, addn. of Et2O and hexane, filtn., washing (Et2O), drying in CO stream, elem. anal.;

DOI:10.1021/om00136a014

Reference yield: 75.0%

IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2 (100896-61-5) + IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2*0.5CH2Cl2 (100815-11-0) → IrCl(CO)RhCl(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2 (100815-12-1)

Guidance literature:

In tetrahydrofuran; complex (as a mixt. of isomers) in THF was refluxed under slow N2 purgefor 15 h to give a suspn. of coral needles in a dark yellow soln.; filtn., washing with THF and Et2O, drying in vacuo, elem. anal.;

DOI:10.1021/om00136a014

upstream raw materials:

IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2

dimethyl acetylenedicarboxylate

Downstream raw materials:

IrCl(CO)RhCl(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2

IrCl(CO)Rh(CO)2(CH₃CO₂C₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*ClO₄^(1-)*0.5CH₂Cl₂

Refernces