87482-56-2

Basic information

• Product Name: IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2
• CAS NO: 87482-56-2
• Molecular Weight: 1183.4
• Mol File: 87482-56-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2(CAS DataBase Reference)
• NIST Chemistry Reference: IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2(87482-56-2)
• EPA Substance Registry System: IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2(87482-56-2)

Safety Data

• Hazardous Substances Data: 87482-56-2(Hazardous Substances Data)

Upstream product

• 15024-82-5 [Ir(CO)(bis(diphenylphosphino)methane)2][Cl] 

Downstream Products

• 100815-11-0 IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2*0.5CH₂Cl₂ 
• 100896-61-5 IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2 
• 100857-91-8 IrCl(CO)RhCl(CF₃C₂CF₃)(((C₆H₅)2P)2CH₂)2*1.5CHCl₃ 

Relevant articles and documents

Heterobimetallic iridium or rhodium μ-bis(diphenylphosphino)methane complexes with copper(I), silver(I), or gold(I). A silver hydride complex and the crystal structure of [(PhC≡C)(OC)Ir(μ-Ph2PCH2PPh2) 2CuCl]

[Ir(dppm)2CO]Cl (dppm = Ph2PCH2PPh2) is used to produce a variety of mixed Ir-Cu, -Ag, -Au, or -Rh complexes containing μ-dppm while [Rh-(dppm)2CO]Cl gives a mixed rhodium-silver complex; the d10 metal ions are readily displaced by Ir(I) or Rh(I) (d8) in transmetalation reactions, and a molecular hydride of silver has been obtained.