t-Butylperoxy-3-cyclohexen-1-carboxylat

Base Information

• Chemical Name: t-Butylperoxy-3-cyclohexen-1-carboxylat
• CAS No.: 946-00-9
• Molecular Formula: C₁₁H₁₈O₃
• Molecular Weight: 198.262
• Mol file: 946-00-9.mol

Synonyms:t-Butylperoxy-3-cyclohexen-1-carboxylat

Chemical Property of t-Butylperoxy-3-cyclohexen-1-carboxylat

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of t-Butylperoxy-3-cyclohexen-1-carboxylat

There total 2 articles about t-Butylperoxy-3-cyclohexen-1-carboxylat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

tert.-butylhydroperoxide (75-91-2) + 1,2,5,6-tetrahydrobenzoic acid (4771-80-6) → t-Butylperoxy-3-cyclohexen-1-carboxylat (946-00-9)

Guidance literature:

tert.-butylhydroperoxide; 1,2,5,6-tetrahydrobenzoic acid; With dmap; In dichloromethane; water; at 0 ℃; for 0.166667h; Inert atmosphere;

With dicyclohexyl-carbodiimide; In dichloromethane; water; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/asia.201800534

Reference yield:

→ t-Butylperoxy-3-cyclohexen-1-carboxylat (946-00-9)

Guidance literature:

tert-Butylhydroperoxid, Tetrahydrobenzoylchlorid;

Reference yield: 74.0%

1,3-Benzothiazole (95-16-9) + t-Butylperoxy-3-cyclohexen-1-carboxylat (946-00-9) → 2-(cyclohex-3-en-1-yl)benzo[d]thiazole

Guidance literature:

With iron(III) trifluoromethanesulfonate; In acetonitrile; at 80 ℃; for 5h; Inert atmosphere; Schlenk technique; Green chemistry;

DOI:10.1021/acs.orglett.6b03287

upstream raw materials:

tert.-butylhydroperoxide

1,2,5,6-tetrahydrobenzoic acid

Downstream raw materials:

(phenyl-2-ethylene) yl-4 cyclohexene trans

Refernces

• 1、 Ye, Changqing,Qian, Bo,Li, Yajun,Su, Min,Li, Daliang,Bao, Hongli. "Iron-Catalyzed Dehydrative Alkylation of Propargyl Alcohol with Alkyl Peroxides to Form Substituted 1,3-Enynes". supporting information. p. 3202 - 3205. Retrieved 2018/06/11.
• 2、 Babu, Kaki Raveendra,Zhu, Nengbo,Bao, Hongli. "Iron-catalyzed C-H alkylation of heterocyclic C-H bonds". supporting information. p. 46 - 49. Retrieved 2017/11/28.