2-Acetylanthracene

Base Information

• Chemical Name: 2-Acetylanthracene
• CAS No.: 10210-32-9
• Molecular Formula: C16H12O
• Molecular Weight: 220.271
• Hs Code.: 2914399090
• DSSTox Substance ID: DTXSID70409167
• Nikkaji Number: J1.023.132I
• Wikidata: Q72434732
• Mol file: 10210-32-9.mol

Synonyms:2-Acetylanthracene;10210-32-9;1-anthracen-2-ylethanone;Ethanone, 1-(2-anthracenyl)-;1-(anthracen-2-yl)ethan-1-one;2-Acetylanthracene, 98%;SCHEMBL1553066;DTXSID70409167;MFCD00156727;AKOS015841092;SB67042;BS-14187;BB 0221151;CS-0076597;FT-0661158;D71111;J-000626;F1905-7214

Chemical Property of 2-Acetylanthracene

Chemical Property:

• Appearance/Colour: Yellow powder
• Vapor Pressure: 8.47E-07mmHg at 25°C
• Melting Point: 189-192 °C(lit.)
• Refractive Index: 1.685
• Boiling Point: 405.894 °C at 760 mmHg
• Flash Point: 180.724 °C
• PSA: 17.07000
• Density: 1.164 g/cm³
• LogP: 4.19560
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: Soluble in Hot Acetone and Hot Benzene.
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 220.088815002
• Heavy Atom Count: 17
• Complexity: 296

Purity/Quality:

99%min ^*data from raw suppliers

2-Acetylanthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)C1=CC2=CC3=CC=CC=C3C=C2C=C1
• Uses: An organic fluorophore 2-Acetylanthracene is used as an organic fluorophore. It is also used as an intermediate in pharmaceuticals.

Technology Process of 2-Acetylanthracene

There total 19 articles about 2-Acetylanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

anthracene (120-12-7) + acetyl chloride (75-36-5) → 2-acetylanthracene (10210-32-9)

Guidance literature:

aluminium trichloride; at 25 ℃; for 0.75h;

DOI:10.1080/00397919808007036

Reference yield: 70.0%

1-(anthracen-2-yl)ethan-1-ol (22371-34-2) → 2-acetylanthracene (10210-32-9)

Guidance literature:

With sodium; In tetrahydrofuran; at 20 ℃; for 20h;

DOI:10.1016/j.tetlet.2009.11.079

Reference yield: 45.1%

anthracene (120-12-7) + acetyl chloride (75-36-5) → 1-acetylanthracene (7396-21-6) + 2-acetylanthracene (10210-32-9)

Guidance literature:

With aluminum (III) chloride; In carbon disulfide; at 0 ℃;

DOI:10.1002/chem.201804139

upstream raw materials:

anthracene

acetyl chloride

acetic anhydride

9-acetylanthracene

Downstream raw materials:

anthracene

C₂₄H₁₆F₃N₃

N-[4-(5-anthracen-2-yl-3-trifluoromethyl-pyrazol-1-yl)-phenyl]-aminosulfonamide

C₂₃H₁₅BF₂O₂

Refernces

• 1、 Garlock,Mosettig. "-". . p. 2255,2257. Retrieved 1945.
• 2、 Ghiaci,Asghari. "Friedel-crafts alkylation and acylation in the absence of solvent". . p. 2213 - 2220. Retrieved 1998.
• 3、 Zhou, Li-Hong,Yu, Xiao-Qi,Pu, Lin. "Na-promoted aerobic oxidation of alcohols to ketones". . p. 475 - 477. Retrieved 2010.
• 4、 Tehrani, M. Barazandeh,Mirkamali,Souri,Foroumadi. "Derivative spectrophotometric method for simultaneous determination of nickel(II) and copper(II) using 6-(anthracen-2-yl)-2,3-dihydro-1,2,4-triazine-3- thione". experimental part. p. 4517 - 4521. Retrieved 2012/08/28.