1-bromo-6-methoxyhexane

Base Information

• Chemical Name: 1-bromo-6-methoxyhexane
• CAS No.: 50592-87-5
• Molecular Formula: C₇H₁₅BrO
• Molecular Weight: 195.1
• Mol file: 50592-87-5.mol

Synonyms:1-bromo-6-methoxyhexane

Chemical Property of 1-bromo-6-methoxyhexane

Chemical Property:

• Refractive Index: 1.458 (589.3 nm 20℃)
• Boiling Point: 112℃ (33 Torr)
• Density: 1.2276 (rough estimate)
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Bromo-6-methoxyhexane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-bromo-6-methoxyhexane

There total 11 articles about 1-bromo-6-methoxyhexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

1-bromo-6-hexanol (4286-55-9) + 1,3-diallyl-6-methoxy-1,3,5-triazine-2,4(1H,3H)-dione → 1-bromo-6-methoxyhexane (50592-87-5)

Guidance literature:

With trifluorormethanesulfonic acid; In 1,4-dioxane; at 20 - 80 ℃; for 7h; Molecular sieve;

DOI:10.1002/ejoc.201900607

Reference yield: 47.2%

1 ,6-dibromohexane (629-03-8) + sodium methylate (124-41-4) → 1-bromo-6-methoxyhexane (50592-87-5)

Guidance literature:

In diethyl ether; ethanol; for 48h; Reflux;

DOI:10.1039/c0dt01321h

Reference yield: 35.0%

methanol (67-56-1) + 1 ,6-dibromohexane (629-03-8) → 1-bromo-6-methoxyhexane (50592-87-5) + 1,6-dimethoxyhexane (13179-98-1)

Guidance literature:

With sodium methylate; potassium iodide; In diethyl ether; Cooling with ice; Reflux; Inert atmosphere;

DOI:10.3762/bjoc.6.57

upstream raw materials:

methanol

1 ,6-dibromohexane

sodium methylate

6-methoxy-hexan-1-ol

Downstream raw materials:

oxepane

1,12-dimethoxydodecane

1,4-bis(6-methoxyhexyl)benzene

6-(diethylamino)hexyl bromide

Refernces

• 1、 Feng, Guitao,Jiao, Xuechen,Karuthedath, Safakath,Laquai, Frédéric,Li, Cheng,Li, Weiwei,Liu, Amelia C. Y.,McNeill, Christopher R.,Tan, Wenliang,Tang, Zheng,Venugopal, Hariprasad,Ye, Long. "Revealing the Side-Chain-Dependent Ordering Transition of Highly Crystalline Double-Cable Conjugated Polymers". supporting information. p. 25499 - 25507. Retrieved 2021/10/25.
• 2、 -. "2-AMINO-1,3,4-THIADIAZINE AND 2-AMINO-1,3,4-OXADIAZINE BASED ANTIFUNGAL AGENTS". Page/Page column 93; 94. . Retrieved 2017/02/09.