Ruthenium(III) chloride hydrate

Base Information

• Chemical Name: Ruthenium(III) chloride hydrate
• CAS No.: 13815-94-6
• Molecular Formula: Cl₃H₆O₃Ru
• Molecular Weight: 261.475
• European Community (EC) Number: 604-667-4
• Mol file: 13815-94-6.mol

Synonyms:Ruthenium(III) chloride hydrate;20759-14-2;ruthenium trichloride hydrate;trichlororuthenium;hydrate;Ruthenium(III)ChlorideHydrate;ruthenium choride hydrate;ruthenium chloride hydrate;MFCD00149844;Ruthenium trichoride hydrate;ruthenium chloride n hydrate;Ruthenium(III)chloride hydrate;ruthenium (iii) chloride hydrate;ruthenium (III) chloride-hydrate;Ruthenium(III) chloride xhydrate;ruthenium(III) trichloride hydrate;ruthenium(III)-trichloride hydrate;ruthenium trichloride monohydrate;H2Cl3ORu;ruthenium chloride, hydrous;ruthenium chloride n-hydrate;ruthenium trichloride, hydrate;ruthenium(+3)chloride hydrate;Ruthenium chloride (RuCl3), monohydrate (8CI,9CI);ruthenium-(iii)-chloride hydrate;ruthenium(iii) chloride n-hydrate;BIXNGBXQRRXPLM-UHFFFAOYSA-K;Ruthenium(III)chloridehydrate(1:x);ruthenium (III) chloride monohydrate;AKOS015855144;CS-O-02285;SY003262;Ruthenium(III) chloride hydrate, Premion?;CS-0031493;Ruthenium(III) chloride hydrate, ReagentPlus(R);Ruthenium(III) chloride hydrate, 38.0-42.0% Ru basis;Ruthenium(III) chloride hydrate (38-43% Ru) (99.9%-Ru);Ruthenium(III) chloride hydrate, >=99.95% Trace metals grade;Ruthenium(III) chloride hydrate, 99.98% trace metals basis;Ruthenium(III) chloride hydrate (40-43% Ru) (99.99+%-Ru) [free of Ru(II) and Ru(IV) by electrochemical analysis]

Chemical Property of Ruthenium(III) chloride hydrate

Chemical Property:

• PSA: 27.69000
• LogP: 1.87560
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 224.821463
• Heavy Atom Count: 5
• Complexity: 8

Purity/Quality:

98% ^*data from raw suppliers

Ruthenium(III) chloride trihydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O.Cl[Ru](Cl)Cl
• Uses: Ruthenium(III) chloride trihydrate (cas# 13815-94-6) is a commonly used catalyst for oxidation reactions. Lewis acid; catalyst for alkyne functionalization and oxidation.

Technology Process of Ruthenium(III) chloride hydrate

There total 10 articles about Ruthenium(III) chloride hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

potassium aquapentachlororuthenate(III) → {RuCl(H2O)5}(2+) (26167-23-7) + ruthenium(III)(H2O)3 chloride (15203-91-5,16904-21-5,13815-94-6,16904-20-4) + dichlorotetraaquoruthenium(III) (100349-08-4,99922-04-0,101314-06-1)

Guidance literature:

In hydrogenchloride; from a 10E-4M soln. of K2(RuCl5H2O) in 0.1M HCl after 74 d at 25°C;; eluation over Dowex-50W, one after another with H2O, 0.1M- and 1M HCl;;

DOI:10.1021/ja01477a014

Reference yield:

aquachlororuthenium(III) (31817-84-2) → {RuCl4(H2O)2}(1-) (44470-29-3,44470-28-2,100017-77-4) + ruthenium(III)(H2O)3 chloride (15203-91-5,16904-21-5,13815-94-6,16904-20-4) + {Ru(H2O)6}(4+) (434332-32-8)

Guidance literature:

In hydrogenchloride; agening process of a soln. of (RuCl5H2O)(2-) in 0.1 M HCl (freshly prepd. from K2RuCl5 and 0.1 M HCl) in a closed tube leads to (RuCl4(H2O)2)(1-),(RuCl3(H2O)3) and at least (Ru(H2O)6)(4+) at ambient temp.;; detn. by electrophoresis and absorption spectra after 0, 1, 3, 6, 10, 25, 45, 88 and 105 d; not isolated;;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + ruthenium(III)chloride (10049-08-8,63767-78-2) → RuCl3*3H2O (13815-94-6,15203-91-5,16904-20-4,16904-21-5) + RuCl3*3H2O (13815-94-6,15203-91-5,16904-20-4,16904-21-5)

Guidance literature:

In hydrogenchloride; 9.2 g commercially avaiable Ru-chloride in 50 ml 0.5 m HCl is refluxed over Hg for 24 h; the mer(trans)-compound is main product;; separation of the two isomeres by ionic exchange chromy. with H2O over Dowex-50 W and Dowex-1 at 0°C (UV-spect. determined); cryoscopic and gravimetric determination of the chemical compn.;;

DOI:10.1021/ja01501a018

upstream raw materials:

aquachlororuthenium(III)

hydrogenchloride

ruthenium(III)chloride

water

Downstream raw materials:

RuCl₃*3H₂O

tris(triphenylphosphine)ruthenium(II) chloride

Refernces