(S)-(+)-4-Methyl-2-pentanol

Base Information Edit

Chemical Name:(S)-(+)-4-Methyl-2-pentanol
CAS No.:14898-80-7
Molecular Formula:C6H14O
Molecular Weight:102.177
Hs Code.:29051900
European Community (EC) Number:623-249-2
DSSTox Substance ID:DTXSID00426387
Nikkaji Number:J75.870A
Wikidata:Q82239316
Mol file:14898-80-7.mol

Synonyms:(S)-(+)-4-Methyl-2-pentanol;14898-80-7;(2S)-4-methylpentan-2-ol;(S)-4-Methylpentan-2-ol;2-Pentanol, 4-methyl-, (2S)-;(s)-4-methyl-2-pentanol;4-methyl (s)-2-pentanol;(s)-4-methyl-pentan-2-ol;(2S)-4-methyl-2-pentanol;SCHEMBL1089695;(S)-1,3-Dimethyl-1-butanol;2-Pentanol,4-methyl-,(2S)-;DTXSID00426387;(S)-(+)-4-Methylpentan-2-ol;MFCD03093078;AKOS025294552;D97160;EN300-1842003;A808829;J-008538

Suppliers and Price of (S)-(+)-4-Methyl-2-pentanol

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(S)-(+)-4-METHYL-2-PENTANOL 95.00%
5G
$ 1224.88

American Custom Chemicals Corporation
(S)-(+)-4-METHYL-2-PENTANOL 95.00%
1G
$ 751.91

Alfa Aesar
(S)-(+)-4-Methyl-2-pentanol, 99%
1g
$ 180.00

Alfa Aesar
(S)-(+)-4-Methyl-2-pentanol, 99%
250mg
$ 57.00

Total 25 raw suppliers

Chemical Property of (S)-(+)-4-Methyl-2-pentanol Edit

Chemical Property:

Appearance/Colour:clear colorless liquid
Refractive Index:n20/D 1.4790(lit.)
Boiling Point:133.5 °C at 760 mmHg
PKA:15.31±0.20(Predicted)
Flash Point:41.1 °C
PSA：20.23000
Density:0.811 g/cm³
LogP:1.41330
Storage Temp.:Flammables area
Water Solubility.:Slightly soluble in water. Soluble in alcohol.
XLogP3:1.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:102.104465066
Heavy Atom Count:7
Complexity:41.4

Purity/Quality:

98%min ^*data from raw suppliers

(S)-(+)-4-METHYL-2-PENTANOL 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi,Xn
Statements: 10-37-66-20
Safety Statements: 24/25-46

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)CC(C)O
Isomeric SMILES:C[C@@H](CC(C)C)O
Uses It is employed in the reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals.

Technology Process of (S)-(+)-4-Methyl-2-pentanol

There total 15 articles about (S)-(+)-4-Methyl-2-pentanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 108-10-1
4-methyl-2-pentanone

: 14898-80-7,72847-31-5
(S)-4-methylpentan-2-ol

: 16404-54-9,72847-31-5
(R)-4-methylpentan-2-ol

Guidance literature:: With methanesulfonic acid; (R,R)-dihydroborate; In pentane; at -20 ℃; for 48h; Title compound not separated from byproducts;
DOI:10.1021/ja00283a042

Reference yield: 40.0%

: 108-11-2,72847-31-5
Methyl isobutyl carbinol

: 108-05-4,9003-20-7
vinyl acetate

: 14898-80-7,72847-31-5
(S)-4-methylpentan-2-ol

: 50373-41-6
(R)-4-methylpentan-2-yl acetate

Guidance literature:: With immobilized lipase B from Candida antarctica; In hexane; at 32 ℃; for 1h; Resolution of racemate; Enzymatic reaction;
DOI:10.3390/molecules17088955

Reference yield:

: 108-10-1
4-methyl-2-pentanone

: 14898-80-7,72847-31-5
(S)-4-methylpentan-2-ol

: 16404-54-9,72847-31-5
(R)-4-methylpentan-2-ol

: 67-64-1
acetone

Guidance literature:: With C₃₄H₃₅BFeN₂O₂; sodium hydroxide; In isopropyl alcohol; at 82 ℃; for 144h; enantioselective reaction;
DOI:10.1002/aoc.5835