2-Methylacrylic acid 2-oxo-tetrahydrofuran-3-yl ester

Base Information

• Chemical Name: 2-Methylacrylic acid 2-oxo-tetrahydrofuran-3-yl ester
• CAS No.: 195000-66-9
• Molecular Formula: C8H10O4
• Molecular Weight: 170.165
• Hs Code.: 2932209090
• European Community (EC) Number: 606-329-1
• DSSTox Substance ID: DTXSID90458652
• Nikkaji Number: J882.446K
• Mol file: 195000-66-9.mol

Synonyms:195000-66-9;2-Methylacrylic acid 2-oxo-tetrahydrofuran-3-yl ester;(2-oxooxolan-3-yl) 2-methylprop-2-enoate;2-Oxooxolan-3-yl methacrylate;2-Propenoic acid, 2-methyl-, tetrahydro-2-oxo-3-furanyl ester;2-oxotetrahydrofuran-3-yl methacrylate;alpha-methacryloyloxy-gamma-butyrolactone;2-Methyl-acrylic acid 2-oxo-tetrahydro-furan-3-yl ester;2-Oxooxolan-3-yl 2-methylprop-2-enoate;butyrolactone methacrylate;ALPHA-METHACRYLOXY-GAMA-BUTYROLACTONE;SCHEMBL70883;a-Methyacryloyloxy-butylolactone;DTXSID90458652;QSUJHKWXLIQKEY-UHFFFAOYSA-N;AMY11181;VHA00066;MFCD19689400;AKOS015910421;tetrahydro-2-oxo-3-furyl methacrylate;2-oxo-tetrahydro-furan-3-yl methacrylate;A-METHYACRYLOYLOXY-|-BUTYLOLACTONE;AS-10133;A-METHYACRYLOYLOXY-|?-BUTYLOLACTONE;O0535;2-Methylacrylicacid2-oxo-tetrahydrofuran-3-ylester

Chemical Property of 2-Methylacrylic acid 2-oxo-tetrahydrofuran-3-yl ester

Chemical Property:

• Vapor Pressure: 0.0014mmHg at 25°C
• Refractive Index: 1.467
• Boiling Point: 296.8 °C at 760 mmHg
• Flash Point: 151.9 °C
• PSA: 52.60000
• Density: 1.17 g/cm³
• LogP: 0.42120
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 170.05790880
• Heavy Atom Count: 12
• Complexity: 231

Purity/Quality:

99.0%, ^*data from raw suppliers

2-Oxotetrahydrofuran-3-yl Methacrylate (stabilized with BHT) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OC1CCOC1=O

Technology Process of 2-Methylacrylic acid 2-oxo-tetrahydrofuran-3-yl ester

There total 3 articles about 2-Methylacrylic acid 2-oxo-tetrahydrofuran-3-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) → 2-oxotetrahydrofuran-3-yl methacrylate (195000-66-9)

Guidance literature:

With triethylamine; In α-bromo-γ-butyrolactone;

Reference yield:

α-bromo-γ-butyrolactone (5061-21-2) + poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 4-methyl-2-pentanone (108-10-1) → 2-oxotetrahydrofuran-3-yl methacrylate (195000-66-9)

Guidance literature:

With sodium hydrogencarbonate; triethylamine;

Reference yield:

→ 2-oxotetrahydrofuran-3-yl methacrylate (195000-66-9)

Guidance literature:

upstream raw materials:

poly(methacrylic acid)

α-bromo-γ-butyrolactone

4-methyl-2-pentanone

Downstream raw materials:

dimethyl 2,2'-azobis(isobutyrate)

Refernces

• 1、 -. "Chemical amplification type positive resist compositions and sulfonium salts". . . Retrieved 2008/06/13.