C₈H₁₉Al

Base Information

• Chemical Name: C₈H₁₉Al
• CAS No.: 1197215-56-7
• Molecular Formula: C₈H₁₉Al
• Molecular Weight: 142.22
• Mol file: 1197215-56-7.mol

Synonyms:C₈H₁₉Al

Chemical Property of C₈H₁₉Al

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₈H₁₉Al

There total 4 articles about C₈H₁₉Al which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

1-hexene (592-41-6,25067-06-5) + trimethylaluminum (75-24-1) → 2-methyl-1-hexene (6094-02-6) + C8H19Al (1197215-56-7) + 1-dimethylalumina-2-methylhexane (1197215-55-6)

Guidance literature:

1-hexene; trimethylaluminum; With C₂₀H₃₀Cl₂Zr^(2-); In dichloromethane; at 22 ℃; for 24h; Inert atmosphere;

With hydrogenchloride; In dichloromethane; water; at 0 ℃;

DOI:10.1016/j.jorganchem.2009.07.037

Reference yield: 14.0%

1-hexene (592-41-6,25067-06-5) + trimethylaluminum (75-24-1) → 2-methyl-1-hexene (6094-02-6) + C8H19Al (1197215-56-7)

Guidance literature:

1-hexene; trimethylaluminum; With bis(cyclopentadienyl)zirconium dichloride; In dichloromethane; at 22 ℃; for 24h; Inert atmosphere;

With hydrogenchloride; In dichloromethane; water; at 0 ℃;

DOI:10.1016/j.jorganchem.2009.07.037

Reference yield:

1-hexene (592-41-6,25067-06-5) + trimethylaluminum (75-24-1) → 2-methyl-1-hexene (6094-02-6) + 2-pentyl-non-1-ene (53056-37-4) + C8H19Al (1197215-56-7) + 1-dimethylalumina-2-methylhexane (1197215-55-6)

Guidance literature:

With zirconocene methyl chloride; In dichloromethane; at 22 ℃; for 24h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique;

DOI:10.1039/c8dt04156c

upstream raw materials:

1-hexene

trimethylaluminum

Refernces

• 1、 Parfenova, Lyudmila V.,Berestova, Tatyana V.,Tyumkina, Tatyana V.,Kovyazin, Pavel V.,Khalilov, Leonard M.,Whitby, Richard J.,Dzhemilev, Usein M.. "Enantioselectivity of chiral zirconocenes as catalysts in alkene hydro-, carbo- and cycloalumination reactions". experimental part. p. 299 - 310. Retrieved 2010/06/14.