Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2

Base Information

• Chemical Name: Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2
• CAS No.: 129570-19-0
• Molecular Formula: C₇₄H₅₀Au₂O₁₂P₄Ru₅
• Molecular Weight: 2154.38
• Mol file: 129570-19-0.mol

Synonyms:Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2

Chemical Property of Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2

There total 7 articles about Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 (97349-41-2) → Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2 (129570-19-0)

Guidance literature:

With Na amalgam; In tetrahydrofuran; N2 atmosphere; reduction of soln. of Ru-compd. in THF with Na amalgam (40 min), addn. of Au-compd., stirring (15 min); filtration (Celite), evapn. (vac.), TLC (2/1 petroleum ether/CH2Cl2); IR and mass spectrometry;

Reference yield: 83.0%

[bis(triphenylphospine)nitrogen(1+)][Co(CO)4] (53433-12-8) + tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate (53317-87-6) + Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 (97349-41-2) → Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2 (129570-19-0) + AuCo*4CO*P(C6H5)3 = AuCo(CO)4(P(C6H5)3) (15154-50-4)

Guidance literature:

In tetrahydrofuran; N2 atmosphere; stirring (room temp. 24 h); removal of solvent (vac.), chromy. (Florisil, 8/1 and 2/1 petroleum ether/CH2Cl2);

Reference yield: 77.0%

[bis(triphenylphospine)nitrogen(1+)][Co(CO)4] (53433-12-8) + tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate (53317-87-6) + Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 (97349-41-2) → Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)2 (129570-19-0) + AuCo*4CO*P(C6H5)3 = AuCo(CO)4(P(C6H5)3) (15154-50-4) + bis(triphenylphosphoranylidene)ammonium tetrafluoroborate

Guidance literature:

In tetrahydrofuran; N2 atmosphere; stirring (room temp. 24 h); removal of solvent (vac.), extn. (CH2Cl2), addn. of Et2O, reduction of volume, cooling (-15°C), filtration of PPN(BF4), evapn. (vac.), TLC (silica gel, 2/1 petroleum ether/CH2Cl2), crystn. (CH2Cl2/petroleum ether); elem. anal.;

upstream raw materials:

{bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}

tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13

[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Co(CO)4]

Downstream raw materials:

Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)11(PPh3)2(P(OEt)3)

Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)11(PPh3)(P(OEt)3)2

Au2Ru5(μ5-C2PPh2)(μ-PPh2)(CO)12(PPh3)(P(OEt)3)

Refernces