Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-

Base Information

• Chemical Name: Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-
• CAS No.: 132182-92-4
• Molecular Formula: C7H3 F13 O
• Molecular Weight: 350.079
• Hs Code.: 2914199090
• European Community (EC) Number: 459-520-5,603-554-7
• DSSTox Substance ID: DTXSID20881338
• Nikkaji Number: J2.192.600K
• Mol file: 132182-92-4.mol

Synonyms:132182-92-4;Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-;3-Methoxyperfluoro(2-methylpentane);1,1,1,2,2,3,4,5,5,5-Decafluoro-3-methoxy-4-(trifluoromethyl)pentane;1,1,1,2,3,4,4,5,5,5-Decafluoro-3-methoxy-2-(trifluoromethyl)pentane;Pentane,1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-;SCHEMBL69418;C7H3F13O;DTXSID20881338;MFCD07784227;AKOS015911184;AS-72660;D4484;NS00018755;E78810;1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane

Chemical Property of Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-

Chemical Property:

• Vapor Pressure: 97.543mmHg at 25°C
• Boiling Point: 100 °C
• Flash Point: 7.172°C
• PSA: 9.23000
• Density: 1.67
• LogP: 4.32910
• Water Solubility.: Insoluble in water
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 3
• Exact Mass: 349.9976308
• Heavy Atom Count: 21
• Complexity: 362

Purity/Quality:

98%, ^*data from raw suppliers

1,1,1,2,2,3,4,5,5,5-Decafluoro-3-methoxy-4-(trifluoromethyl)pentane >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(C(C(F)(F)F)(C(F)(F)F)F)(C(C(F)(F)F)(F)F)F
• Uses: 1,1,1,2,2,3,4,5,5,5-Decafluoro-3-methoxy-4-(trifluoromethyl)pentane is used in preparation method of isolated Hydrofluoroether.

Technology Process of Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-

There total 6 articles about Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.83%

Methyl methanesulfonate (66-27-3) + 1,1,1,3,4,4,5,5,5-nonafluoro-2-trifluoromethyl-2,3-epoxypentane (788-67-0) → 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane (132182-92-4)

Guidance literature:

With potassium fluoride; 18-crown-6 ether; In diethylene glycol dimethyl ether; at 50 ℃; for 5h; Temperature;

Reference yield: 79.56%

perfluoro-2-hexanone (755-27-1) + dimethyl sulfate (77-78-1) → 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane (132182-92-4)

Guidance literature:

perfluoro-2-hexanone; With potassium fluoride; In diethylene glycol dimethyl ether; at 20 ℃; for 4h;

dimethyl sulfate; In diethylene glycol dimethyl ether; at 20 ℃; for 72h;

Reference yield: 72.0%

2,3-bi(fluorosulfato)perfluoro-4-methylpentane (75677-98-4) + dimethyl sulfate (77-78-1) → 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane (132182-92-4)

Guidance literature:

With cesium fluoride; In N,N-dimethyl-formamide; at 20 ℃; for 4h;

DOI:10.1007/BF00958252

upstream raw materials:

2,3-bi(fluorosulfato)perfluoro-4-methylpentane

dimethyl sulfate

perfluoro-2-methylpentan-3-one

perfluoro-2-hexanone

Refernces

• 1、 -. "Perfluoroalkyl haloalkyl ethers and compositions and applications thereof". Page/Page column 13-14. . Retrieved 2008/06/13.