1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene

Base Information

• Chemical Name: 1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene
• CAS No.: 146791-31-3
• Molecular Formula: C₁₃H₂₀O₂Si
• Molecular Weight: 236.386
• Mol file: 146791-31-3.mol

Synonyms:1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene

Chemical Property of 1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene

There total 2 articles about 1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-methyl-2-phenyl-1,3-dioxolane (3674-77-9) + trimethylsilyl trifluoromethanesulfonate (27607-77-8) → 1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene (146791-31-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In dichloromethane; for 24h; Ambient temperature;

DOI:10.1021/jo00058a027

Reference yield:

chloro-trimethyl-silane (75-77-4) + 2-methyl-2-phenyl-1,3-dioxolane (3674-77-9) → 1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene (146791-31-3)

Guidance literature:

With triethylamine; sodium iodide; In acetonitrile; for 1.5h; Yield given; Heating;

DOI:10.1021/jo00086a046

Reference yield:

1-<2-<(trimethylsilyl)oxy>ethoxy>-1-phenylethene (146791-31-3) → <1-(2-Hydroxyethoxy)ethenyl>benzene (108415-97-0)

Guidance literature:

With potassium carbonate; In methanol; for 0.666667h; Yield given;

DOI:10.1021/jo00086a046

upstream raw materials:

chloro-trimethyl-silane

2-methyl-2-phenyl-1,3-dioxolane

trimethylsilyl trifluoromethanesulfonate

Downstream raw materials:

<1-(2-Hydroxyethoxy)ethenyl>benzene

<1-(2-n-Butoxyethoxy)ethenyl>benzene

Refernces

• 1、 Gassman, Paul G.,Burns, Stephen J.,Pfister, Keith B.. "Synthesis of Cyclic and Acyclic Enol Ethers (Vinyl Ethers)". . p. 1449 - 1457. Retrieved 2007/10/02.