P₅I₂⁽¹⁺⁾*[Al(OC(CF₃)3)4]^(1-)=P₅I₂[Al(OC(CF₃)3)4]

Base Information

• Chemical Name: P₅I₂⁽¹⁺⁾*[Al(OC(CF₃)3)4]^(1-)=P₅I₂[Al(OC(CF₃)3)4]
• CAS No.: 402956-18-7
• Molecular Formula: C₁₆AlF₃₆O₄*I₂P₅
• Molecular Weight: 1375.78
• Mol file: 402956-18-7.mol

Synonyms:P₅I₂⁽¹⁺⁾*[Al(OC(CF₃)3)4]^(1-)=P₅I₂[Al(OC(CF₃)3)4]

Chemical Property of P₅I₂⁽¹⁺⁾*[Al(OC(CF₃)3)4]^(1-)=P₅I₂[Al(OC(CF₃)3)4]

Chemical Property:

Purity/Quality:

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Technology Process of P₅I₂⁽¹⁺⁾*[Al(OC(CF₃)3)4]^(1-)=P₅I₂[Al(OC(CF₃)3)4]

There total 4 articles about P₅I₂⁽¹⁺⁾*[Al(OC(CF₃)3)4]^(1-)=P₅I₂[Al(OC(CF₃)3)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[Ag(η2-P4)2][Al(OC(CF3)3)4] (345901-94-2) + iodine (7553-56-2,12190-71-5,8031-47-8) → diphosphorus tetraiodide (13455-00-0) + phosphorous (12185-10-3) + P5I2(1+)*[Al(OC(CF3)3)4](1-)=P5I2[Al(OC(CF3)3)4] (402956-18-7) + phosphorous triiodide (13455-01-1) + silver(I) iodide

Guidance literature:

In dichloromethane-d2; I2 was sublimed into the complex at 77 K after CH2Cl2, stored at -80°C and every 30 min heavily shaken for about 1 min (10 times), 4 days(inert atm.); ppt. was filtered at -80°C, volatiles were quickly removed at 0°C; elem. anal.;

DOI:10.1039/b103957c

Reference yield: 92.0%

Ag(1+)*2P4*[Al(OC(CF3)3)4](1-)=Ag(P4)2[Al(OC(CF3)3)4] + iodine (7553-56-2,12190-71-5,8031-47-8) → phosphorous (12185-10-3) + diphosphorous tetraiodide + P5I2(1+)*[Al(OC(CF3)3)4](1-)=P5I2[Al(OC(CF3)3)4] (402956-18-7) + phosphorous triiodide (13455-01-1)

Guidance literature:

In dichloromethane; byproducts: AgI; Sonication; under N2 or Ar atm.; I2 sublimed onto the solid Ag(P4)2Al(OC(CF3)3)4 at 77 K, then CH2Cl2 condensed onto mixt.; placed in dry ice/2-propanol bath; then stored at -80 °C with heavy shaking; soln. filtered; volatiles removed at 0 °C;

DOI:10.1002/1521-3773(20011203)40:23<4406::AID-ANIE4406>3.0.CO;2-X

Reference yield:

Ag(1+)*2P4*[Al(OC(CF3)3)4](1-)=Ag(P4)2[Al(OC(CF3)3)4] + iodine (7553-56-2,12190-71-5,8031-47-8) → phosphorous (12185-10-3) + P5I2(1+)*[Al(OC(CF3)3)4](1-)=P5I2[Al(OC(CF3)3)4] (402956-18-7) + phosphorous triiodide (13455-01-1) + silver(I) iodide

Guidance literature:

In dichloromethane-d2; Sonication; in situ; under N2 or Ar atm.; I2 sublimed onto the solid Ag(P4)2Al(OC(CF3)3)4 at 77 K, then CD2Cl2 condensed onto mixt.; sealed in NMR tube, placed in dry ice/2-propanol bath, activated by ultrasound at -78 °Cfor 10 min); without isolation, detd. by (31)P NMR, (27)Al NMR, (13)C NMR;

DOI:10.1002/1521-3773(20011203)40:23<4406::AID-ANIE4406>3.0.CO;2-X

upstream raw materials:

[Ag(η2-P4)2][Al(OC(CF3)3)4]

iodine

Refernces

• 1、 Krossing, Ingo. "Reactions of P4 and I2 with Ag[Al(OC(CF3)3)4]: From elusive polyphosphorus cations to subvalent P3I6+ and phosphorus rich P5I2+". . p. 500 - 512. Retrieved 2007/10/03.