ETHYL 2,3,3,3-TETRAFLUOROPROPIONATE

Base Information

• Chemical Name: ETHYL 2,3,3,3-TETRAFLUOROPROPIONATE
• CAS No.: 399-92-8
• Molecular Formula: C5H6F4O2
• Molecular Weight: 174.095
• Hs Code.: 2915900090
• Mol file: 399-92-8.mol

Synonyms:Propionicacid, 2,3,3,3-tetrafluoro-, ethyl ester (6CI,8CI);Ethyl2,3,3,3-tetrafluoropropanoate;Ethyl 2,3,3,3-tetrafluoropropionate;

Chemical Property of ETHYL 2,3,3,3-TETRAFLUOROPROPIONATE

Chemical Property:

• Vapor Pressure: 29.5mmHg at 25°C
• Refractive Index: 1.38
• Boiling Point: 105.5 °C at 760 mmHg
• Flash Point: 18.2 °C
• PSA: 26.30000
• Density: 1.272 g/cm³
• LogP: 1.44990

Purity/Quality:

98%min ^*data from raw suppliers

Ethyl2,3,3,3-Tetrafluoropropionate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

Useful:

Technology Process of ETHYL 2,3,3,3-TETRAFLUOROPROPIONATE

There total 11 articles about ETHYL 2,3,3,3-TETRAFLUOROPROPIONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

ethanol (64-17-5) + N,N'-diethyl-1,2,2,2-tetrafluoropropionamide (392-63-2) → 2,3,3,3-tetrafluoropropionic acid ethyl ester (399-92-8)

Guidance literature:

With hydrogenchloride; sodium aluminate; In water; at 130 ℃; for 10h; Reagent/catalyst; Catalytic behavior;

Reference yield: 94.0%

1,1,2,3,3,3-hexafluoropropyl ethyl ether (380-34-7) → 2,3,3,3-tetrafluoropropionic acid ethyl ester (399-92-8)

Guidance literature:

With sulfuric acid; at 40 ℃; for 1h;

DOI:10.1023/B:RJAC.0000024585.14553.5f

Reference yield: 77.0%

ethyl 2,3-dibromotrifluoropropionate (379-05-5) → 2,3,3,3-tetrafluoropropionic acid ethyl ester (399-92-8) + 2-bromo-2,3,3,3-tetrafluoropropionic acid ethyl ester (10186-73-9)

Guidance literature:

With cesium fluoride; In diethylene glycol dimethyl ether; at 100 ℃; for 4h;

DOI:10.1007/BF00960271

upstream raw materials:

perfluoropropylene

ethanol

1,1,2,3,3,3-hexafluoropropyl ethyl ether

6-(1,2,2,2-Tetrafluoro-ethyl)-[1,3,2,4,5]dioxadithiazine 2,2,4,4-tetraoxide

Downstream raw materials:

2,3,3,3-Tetrafluoro-2-(1-hydroxy-cyclohex-2-enyl)-propionic acid ethyl ester

2,3,3,3-Tetrafluoro-2-(3-oxo-cyclohexyl)-propionic acid ethyl ester

fluoromalonic acid diethyl ester

2,3,3,3-Tetrafluoro-2-(1-hydroxy-cyclohexyl)-propionic acid ethyl ester

Refernces

• 1、 -. "Synthesis method of 2,3,3,3-tetrafluoropropionate". Paragraph 0033; 0034. . Retrieved 2017/02/17.
• 2、 Il'in,Bakhmutov,Ivanova,Furin,Tolstikova,Sukhinin. "Synthesis and use of partially fluorinated dialkyl ethers derived from hexafluoropropylene". . p. 98 - 101. Retrieved 2007/10/03.