POTASSIUM (4-BUTOXYPHENYL)TRIFLUOROBORATE

Base Information

• Chemical Name: POTASSIUM (4-BUTOXYPHENYL)TRIFLUOROBORATE
• CAS No.: 850623-61-9
• Molecular Formula: C10H13 B F3 O . K
• Molecular Weight: 256.117
• Hs Code.: 2931900090
• Mol file: 850623-61-9.mol

Synonyms:POTASSIUM (4-N-BUTOXY)PHENYLTRIFLUOROBORATE;POTASSIUM (4-BUTOXYPHENYL)TRIFLUOROBORATE;Potassium (4-butoxyphenyl)trifluorate;Potassium (4-butoxyphenyl)trifluoroborate 96%;Potassium(4-butoxyphenyl)trifluoroborate96%;Potassium (4-n-butoxyphenyl)trifluorate

Chemical Property of POTASSIUM (4-BUTOXYPHENYL)TRIFLUOROBORATE

Chemical Property:

• Melting Point: >300ºC
• PSA: 9.23000
• LogP: 2.91990

Purity/Quality:

98%min ^*data from raw suppliers

Potassium (4-butoxyphenyl)trifluoroborate 96% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POTASSIUM (4-BUTOXYPHENYL)TRIFLUOROBORATE

There total 1 articles about POTASSIUM (4-BUTOXYPHENYL)TRIFLUOROBORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium hydrogen difluoride + 4-butoxyphenylboronic acid (105365-51-3) → potassium (4-butoxyphenyl)trifluoroborate (850623-61-9)

Guidance literature:

With water; In methanol; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/ejoc.201300529

Reference yield: 75.0%

potassium (4-butoxyphenyl)trifluoroborate (850623-61-9) → 4-fluorobenzyl-n-butylether (78649-25-9)

Guidance literature:

With lithium hydroxide monohydrate; silver trifluoromethanesulfonate; Selectfluor; In ethyl acetate; at 55 ℃; Sealed tube;

DOI:10.1016/j.tet.2014.10.055

Reference yield: 60.0%

potassium (4-butoxyphenyl)trifluoroborate (850623-61-9) + (trifluoromethyl)trimethylsilane (81290-20-2) → 1-butoxy-4-[(trifluoromethyl)thio]benzene

Guidance literature:

With potassium phosphate; 1,10-Phenanthroline; copper(I) thiocyanate; sulfur; silver carbonate; In N,N-dimethyl-formamide; toluene; at 70 ℃; for 20h; Inert atmosphere; Molecular sieve; Sealed tube;

DOI:10.1055/s-0035-1561565

upstream raw materials:

4-butoxyphenylboronic acid

Downstream raw materials:

4-fluorobenzyl-n-butylether

1-butoxy-2-fluorobenzene

Refernces