Bis(4-tert-butylphenyl)iodonium hexafluorophosphate

Base Information

• Chemical Name: Bis(4-tert-butylphenyl)iodonium hexafluorophosphate
• CAS No.: 61358-25-6
• Molecular Formula: C20H26F6IP
• Molecular Weight: 538.295
• Hs Code.: 29319090
• Mol file: 61358-25-6.mol

Synonyms:Bis(4-t-butyl phenyl)iodonium hexafluorophosphate;

Chemical Property of Bis(4-tert-butylphenyl)iodonium hexafluorophosphate

Chemical Property:

• Vapor Pressure: 0Pa at 25℃
• Melting Point: 174 °C
• PSA: 13.59000
• Density: 1.57g/cm3 at 21℃
• LogP: 5.79240
• Solubility.: soluble in Ethanol

Purity/Quality:

99.9% ^*data from raw suppliers

Bis(4-(tert-butyl)phenyl)iodoniumHexafluorophosphate(V) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 36/37/38-34
• Safety Statements: 26-36-45-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Bis(4-(tert-butyl)phenyl)iodonium hexafluorophosphate(V) is an organic catalyst used for the photoinduced thermal polymerization reactions.

Technology Process of Bis(4-tert-butylphenyl)iodonium hexafluorophosphate

There total 1 articles about Bis(4-tert-butylphenyl)iodonium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-butylbenzene (253185-03-4,253185-04-5) → bis(4-tert-butylphenyl)iodonium hexafluorophosphate (61358-25-6)

Guidance literature:

tert-butylbenzene; With iodine; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 40 ℃; for 0.25h;

With trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 12h;

With sodium hexaflorophosphate; In dichloromethane; water; at 20 ℃; for 12h;

DOI:10.1021/acs.orglett.1c03319

Reference yield: 88.0%

C21H16N2 + bis(4-tert-butylphenyl)iodonium hexafluorophosphate (61358-25-6) → C41H42N2(2+)*2F6P(1-)

Guidance literature:

C₂₁H₁₆N₂; bis(4-tert-butylphenyl)iodonium hexafluorophosphate; With copper(II) acetate monohydrate; In N,N-dimethyl-formamide; at 100 ℃; for 30h;

With tetrabutyl ammonium fluoride; In acetonitrile;

With ammonium hexafluorophosphate; In water; at 20 ℃; for 3h;

Reference yield: 72.0%

1-acetyl-1H-benzotriazole (18773-93-8) + bis(4-tert-butylphenyl)iodonium hexafluorophosphate (61358-25-6) → 1-(4-tert-butylphenyl)-1H-1,2,3-benzotriazole

Guidance literature:

With copper; caesium carbonate; In acetonitrile; at 80 ℃; for 24h;

DOI:10.1016/j.jorganchem.2019.05.013

upstream raw materials:

tert-butylbenzene

Downstream raw materials:

fluorobenzene

iodobenzene

4-tert-Butyl-phenylradikal

methoxybenzene

Refernces