Phthalocyanine tin(IV) dichloride

Base Information

• Chemical Name: Phthalocyanine tin(IV) dichloride
• CAS No.: 18253-54-8
• Molecular Formula: C32H16Cl2N8Sn
• Molecular Weight: 702.149
• Hs Code.: 29310099
• European Community (EC) Number: 658-055-7
• DSSTox Substance ID: DTXSID401014802
• Mol file: 18253-54-8.mol

Synonyms:Phthalocyanine tin(IV) dichloride;Dichloro[phthalocyaninato(2-)]tin;DTXSID401014802;P0997

Chemical Property of Phthalocyanine tin(IV) dichloride

Chemical Property:

• Appearance/Colour: purple crystalline powder
• PSA: 65.32000
• LogP: 2.46260
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 0
• Exact Mass: 701.989700
• Heavy Atom Count: 43
• Complexity: 709

Purity/Quality:

98% ^*data from raw suppliers

Tin(IV) phthalocyanine dichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 36/37/38-43-38-36-25
• Safety Statements: 24/25-45-36/37-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=C6C=CC=CC6=C([N-]5)N=C7C8=CC=CC=C8C(=N7)N=C2[N-]3)C9=CC=CC=C94.[Cl-].[Cl-].[Sn+4]
• Uses: Tin(IV) phthalocyanine dichloride is a stable metal phthalocyanine dye.

Technology Process of Phthalocyanine tin(IV) dichloride

There total 6 articles about Phthalocyanine tin(IV) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

phthalonitrile (91-15-6) + tin(ll) chloride → phthalocyanine tin(IV) dichloride (18253-54-8)

Guidance literature:

In further solvent(s); SnCl2 and phthalonitrile were added to 1-chloronaphthalene (solvent); brought to reflux over a period of 1 h; was allowed to reflux for 3 h; cooled slowly to room temperature; filtered; washed in benzene in a Soxhlet extractor for 24 h; elem. anal.;

DOI:10.1021/ja00344a022

Reference yield:

tin(IV) chloride (7646-78-8) + phthalonitrile (91-15-6) → phthalocyanine tin(IV) dichloride (18253-54-8)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In pentan-1-ol; at 136 ℃; for 10h;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + diiodo(phthalocyaninato-κ(4))tin(IV) (12102-35-1) → phthalocyanine tin(IV) dichloride (18253-54-8)

Guidance literature:

In water; benzene;

DOI:10.1016/j.molstruc.2016.10.070

upstream raw materials:

phthalonitrile

hydrogenchloride

diiodo(phthalocyaninato-κ(4))tin(IV)

phthalocyaninatotin(II)

Downstream raw materials:

phthalocyaninatotin(II)

Refernces

• 1、 Kubiak, Ryszard,Dyrda, Gabriela,Ejsmont, Krzysztof. "Examples of UV–Vis profiles use as tool for evidence of the metallophthalocyanines transformation". . p. 559 - 564. Retrieved 2017.
• 2、 Janczak, Jan,Kubiak, Ryszard. "Two isomorphous complexes: Dichloro[phthalocyaninato(2-)]tin(IV) and dichloro[phthalocyaninato(2-)]-germanium(IV)". . p. m237-m240. Retrieved 2007/10/03.