Phthalocyanine Tin(II)

Base Information

• Chemical Name: Phthalocyanine Tin(II)
• CAS No.: 15304-57-1
• Molecular Formula: C32H16N8Sn
• Molecular Weight: 631.23
• DSSTox Substance ID: DTXSID00424848
• Mol file: 15304-57-1.mol

Synonyms:Phthalocyanine Tin(II);2,11,20,29,37,38-Hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene;tin(2+);[Phthalocyaninato(2-)]tin;DTXSID00424848;tin(2+) phthalocyanine-29,31-diide;P1024;9,18,27,36,37,39,40,41-octaza-38lambda2-stannadecacyclo[17.17.3.110,17.128,35.02,7.08,37.011,16.020,25.026,39.029,34]hentetraconta-1,3,5,7,9,11,13,15,17(41),18,20,22,24,26,28(40),29,31,33,35-nonadecaene

Chemical Property of Phthalocyanine Tin(II)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 84.02000
• Density: g/cm³
• LogP: 1.08360
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 632.051995
• Heavy Atom Count: 41
• Complexity: 709

Purity/Quality:

98% ^*data from raw suppliers

Tin(II) Phthalocyanine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=C6C=CC=CC6=C([N-]5)N=C7C8=CC=CC=C8C(=N7)N=C2[N-]3)C9=CC=CC=C94.[Sn+2]
• Uses: Tin(II) phthalocyanine (CAS# 15304-57-1) is an organometallic cyanine dye. Tin(II) phthalocyanine has been used in the preparation of Fe-Sn macrocycles, magnetic radicals with charge transfer properties.

Technology Process of Phthalocyanine Tin(II)

There total 7 articles about Phthalocyanine Tin(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

phthalonitrile (91-15-6) + tin(ll) chloride → phthalocyaninatotin(II) (15304-57-1)

Guidance literature:

With 1,8-diazabicyclo{5.4.0}undec-7-ene; In cellosolve=2-ethoxyethanol; a mixt. of the Cu salt, phthalonitrile, and the base (molar ratio 3:10:10) was refluxed in ethyl-cellosolve for 6 h;; the ppt. was filtered off, washed with water and ethanol, and purified by extrn. with CHCl3; IR, UV, XRD, and elem.anal.;;

DOI:10.1246/cl.1983.313

Reference yield:

tin (7440-31-5) + phthalonitrile (91-15-6) → phthalocyaninatotin(II) (15304-57-1)

Guidance literature:

In neat (no solvent, solid phase); heating a mixture of components in an evacuated sealed glass tube at 210°C for 1 week;

DOI:10.1016/0925-8388(92)90054-D

Reference yield:

AuSn4 + phthalonitrile (91-15-6) → phthalocyaninatotin(II) (15304-57-1)

Guidance literature:

In neat (no solvent, solid phase); byproducts: Au; heating a mixture of components in an evacuated sealed glass tube at 210°C for 1 week;

DOI:10.1016/0925-8388(92)90054-D

upstream raw materials:

tin

phthalonitrile

phthalocyanine tin(IV) dichloride

tin(II)

Downstream raw materials:

phthalocyanine tin(IV) dichloride

Refernces

• 1、 Kao, Po-Ching,Chu, Sheng-Yuan,Liu, Shyh-Jiun,You, Zong-Xian,Chuang, Chan-An. "Improved performance of organic light-emitting diodes using a metal-phthalocyanine hole-injection layer". . p. H122-H126. Retrieved 2008/10/09.
• 2、 Tomoda, Haruhiko,Saito, Shojiro,Shiraishi, Shinsaku. "SYNTHESIS OF METALLOPHTHALOCYANINES FROM PHTALONITRILE WITH STRONG ORGANIC BASES". . p. 313 - 316. Retrieved 2007/10/02.