ethyl phenyl trithiocarbonate

Base Information

• Chemical Name: ethyl phenyl trithiocarbonate
• CAS No.: 77102-69-3
• Molecular Formula: C₉H₁₀S₃
• Molecular Weight: 214.376
• Mol file: 77102-69-3.mol

Synonyms:ethyl phenyl trithiocarbonate

Chemical Property of ethyl phenyl trithiocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of ethyl phenyl trithiocarbonate

There total 6 articles about ethyl phenyl trithiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

carbon disulfide (75-15-0,12122-00-8) + ethyl iodide (75-03-6) + thiophenol (108-98-5) → ethyl phenyl trithiocarbonate (77102-69-3)

Guidance literature:

thiophenol; With triethylamine; at 25 ℃; for 0.25h; Neat (no solvent);

carbon disulfide; In water; at 25 ℃; for 0.5h;

ethyl iodide; In water; at 25 ℃; for 2.67h; in air atmosphere;

DOI:10.1007/s00706-008-0864-x

Reference yield: 75.0%

diphenyliodonium chloride (1483-72-3) + potassium ethyltrithiocarbonate (35444-20-3) → ethyl phenyl trithiocarbonate (77102-69-3)

Guidance literature:

With 1-butyl-3-methylimidazolium Tetrafluoroborate; at 60 ℃; for 3h;

Reference yield: 63.0%

phenyl chlorodithioformate (16911-89-0) + ethanethiol (75-08-1) → ethyl phenyl trithiocarbonate (77102-69-3)

Guidance literature:

DOI:10.1039/P29880000177

upstream raw materials:

carbon disulfide

ethyl iodide

thiophenol

ethyl bromide

Downstream raw materials:

ethene

Ethyl phenyl sulfide

thiophenol

diethyl sulphide

Refernces

• 1、 Wang, Feng-Yan,Chen, Zhen-Chu,Zheng, Qin-Guo. "Organic reactions in ionic liquids: Synthesis of alkyl aryl trithiocarbonates by the S-arylation of potassium carbonotrithioates with diaryliodonium salts". . p. 810 - 811. Retrieved 2007/10/03.
• 2、 Sugawara,Shirahata,Sato,Sato. "ONE-POT SYNTHESIS OF ALKYL ARYL TRITHIOCARBONATES FROM BENZENETHIOLS, ALKYL HALIDES, AND CARBON DISULFIDE WITH A PHASE-TRANSFER CATALYST.". . p. 3353 - 3354. Retrieved 2007/10/02.