ETHYL PHENYL SULFIDE

Base Information

• Chemical Name: ETHYL PHENYL SULFIDE
• CAS No.: 622-38-8
• Molecular Formula: C8H10S
• Molecular Weight: 138.233
• Hs Code.: 2930909090
• European Community (EC) Number: 210-731-9
• NSC Number: 75124
• UNII: UV3WD52QZX
• DSSTox Substance ID: DTXSID60211236
• Nikkaji Number: J43.573B
• Wikidata: Q27451730
• Mol file: 622-38-8.mol

Synonyms:Sulfide,ethyl phenyl (6CI,8CI);(Ethylthio)benzene;(Phenylthio)ethane;Ethyl phenylsulfide;NSC 75124;Phenyl ethyl sulfide;Thiophenetole;

Chemical Property of ETHYL PHENYL SULFIDE

Chemical Property:

• Appearance/Colour: clear colorless to light yellow liquid
• Melting Point: -35.21 °C
• Refractive Index: n20/D 1.566(lit.)
• Boiling Point: 202.9 °C at 760 mmHg
• Flash Point: 73.9 °C
• PSA: 25.30000
• Density: 1.021g/cm³
• LogP: 2.79860
• Storage Temp.: 2-8°C
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 138.05032149
• Heavy Atom Count: 9
• Complexity: 65

Purity/Quality:

99.5% ^*data from raw suppliers

Ethyl Phenyl Sulfide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,T
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCSC1=CC=CC=C1
• Uses: Ethyl Phenyl Sulfide is a reactant used in the synthesis of polyoxometalates for layered double hydroxides. Also used in the preparation of immobilized manganese porphyrin on functionalizedmagnetic nanoparticles

Technology Process of ETHYL PHENYL SULFIDE

There total 144 articles about ETHYL PHENYL SULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

thiophenol (108-98-5) → Ethyl phenyl sulfide (622-38-8)

Guidance literature:

With potassium carbonate; sodium iodide; In water; at 140 ℃; Microwave irradiation;

DOI:10.1039/d0ob01966f

Reference yield: 95.0%

iodobenzene (591-50-4) + ethanethiol (75-08-1) → Ethyl phenyl sulfide (622-38-8)

Guidance literature:

With potassium hydroxide; copper(II) oxide; In dimethyl sulfoxide; at 80 ℃; for 4h;

DOI:10.1002/anie.200701282

Reference yield: 93.0%

ethyl bromide (74-96-4) + diphenyldisulfane (882-33-7) → Ethyl phenyl sulfide (622-38-8)

Guidance literature:

With water; rongalite; potassium carbonate; In N,N-dimethyl-formamide; for 0.25h;

DOI:10.1055/s-2006-950363

upstream raw materials:

2-ethoxyquinoline

thiophenol

ethyl bromide

sodium thiophenolate

Downstream raw materials:

4,4'-bis-ethylsulfanyl-benzophenone

ethyl-pentachlorophenyl sulfide

1-[4-(ethylsulfanyl)phenyl]ethan-1-one

ethylmercapto-4 benzophenone

Refernces

• 1、 Anselmi, Silvia,Liu, Siyu,Kim, Seong-Heun,Barry, Sarah M.,Moody, Thomas S.,Castagnolo, Daniele. "A mild and chemoselective CALB biocatalysed synthesis of sulfoxides exploiting the dual role of AcOEt as solvent and reagent". supporting information. p. 156 - 161. Retrieved 2021/01/14.
• 2、 Lu, Kui,Lv, Ming-Xiu,Mai, Wen-Peng,Sui, Hong-Da. "Nickel-catalyzed carbonylation of thioacetates with aryl iodides via CO insertion and C–S bond cleavage". . p. 890 - 895. Retrieved 2021/07/02.