p-Toluenesulfinyl azide

Base Information

• Chemical Name: p-Toluenesulfinyl azide
• CAS No.: 40560-76-7
• Molecular Formula: C₇H₇N₃OS
• Molecular Weight: 181.218
• DSSTox Substance ID: DTXSID00702310
• Mol file: 40560-76-7.mol

Synonyms:p-Toluenesulfinyl azide;DTXSID00702310;40560-76-7

Chemical Property of p-Toluenesulfinyl azide

Chemical Property:

• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 181.03098303
• Heavy Atom Count: 12
• Complexity: 217

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)S(=O)N=[N+]=[N-]

Technology Process of p-Toluenesulfinyl azide

There total 1 articles about p-Toluenesulfinyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di(p-tolyl) disulfide (103-19-5) → tosyl azide (40560-76-7)

Guidance literature:

Multistep reaction; (i) Cl₂, Ac₂O, CH₂Cl₂, (ii) NaN₃, MeCN;

DOI:10.1021/ja00832a026

Reference yield:

Methyl p-tolyl sulfoxide (934-72-5) + tosyl azide (40560-76-7) → C15H17NO2S2 (4235-12-5,24702-26-9,37831-86-0)

Guidance literature:

In acetonitrile;

DOI:10.1021/ja00832a026

Reference yield:

tosyl azide (40560-76-7) + dimethyl sulfoxide (67-68-5,8070-53-9) → S,S-dimethyl-N-p-tolylsulfonylsulfimine (13150-75-9)

Guidance literature:

In acetonitrile;

DOI:10.1021/ja00832a026

upstream raw materials:

di(p-tolyl) disulfide

Downstream raw materials:

C₁₅H₁₇NO₂S₂

S,S-dimethyl-N-p-tolylsulfonylsulfimine