Methane-d2, diazo-(6CI,7CI,8CI,9CI)

Base Information

• Chemical Name: Methane-d2, diazo-(6CI,7CI,8CI,9CI)
• CAS No.: 14621-84-2
• Molecular Formula: CD2 N2
• Molecular Weight: 44.0244
• Mol file: 14621-84-2.mol

Synonyms:Diazomethane-d2;Dideuteriodiazomethane

Chemical Property of Methane-d2, diazo-(6CI,7CI,8CI,9CI)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: An explosive. When heated to decomposition it emits toxic fumes of NOx. See also DIAZ"> x. See also DIAZOMETHANE." target="_blank">An explosive. When heated to decomposition it emits toxic fumes of NOx. See also DIAZ

MSDS Files:

Useful:

Technology Process of Methane-d2, diazo-(6CI,7CI,8CI,9CI)

There total 5 articles about Methane-d2, diazo-(6CI,7CI,8CI,9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-methyl-d3-N-nitroso-para-toluenesulfonamide (42366-72-3) → diazomethane-d2 (14621-84-2)

Guidance literature:

With water-d2; sodium; In diethyl ether; at 70 ℃;

DOI:10.1021/ja00256a024

Reference yield:

N-methyl-N-nitrosotoluene-p-sulfonamide (80-11-5) → diazomethane-d2 (14621-84-2)

Guidance literature:

With deuteriated sodium hydroxide; In diethyl ether; water-d2; at 70 ℃; for 1h;

DOI:10.1021/ja00330a050

Reference yield:

1-methyl-1-nitrosourea (684-93-5) → diazomethane-d2 (14621-84-2)

Guidance literature:

With deuteriated sodium hydroxide; In 1,2-dimethoxyethane; water-d2;

DOI:10.1021/ja00303a024

upstream raw materials:

N-nitroso-N-trideuteriomethyl-urea

1-methyl-1-nitrosourea

N-methyl-d₃-N-nitroso-para-toluenesulfonamide

N-methyl-N-nitrosotoluene-p-sulfonamide

Downstream raw materials:

paraformaldehyde-d2

ethyl methyl ether

ethylpropylether

2-butyl ethyl ether

Refernces

• 1、 Markey,Shaw. "". . p. 3414. Retrieved 1978.
• 2、 Hecht,Kozarich. "". . p. 1501. Retrieved 1972.
• 3、 Haiss, Peter,Zeller, Klaus-Peter. "Partial oxygen migration in the photochemical wolff rearrangement - α-Oxocarben-Oxiren-isomerization or intermolecular mechanism?". . p. 595 - 605. Retrieved 2007/10/03.
• 4、 Olah, George A.,Doggweiler, Hans,Felberg, Jeff D.. "Onium Ylide Chemistry. 4. Alkylhalonium Methylides". . p. 4975 - 4978. Retrieved 2007/10/02.