Tin(IV) acetate

Base Information

• Chemical Name: Tin(IV) acetate
• CAS No.: 2800-96-6
• Molecular Formula: C₄H₆O₄Sn
• Molecular Weight: 236.799
• Hs Code.: 29152900
• European Community (EC) Number: 628-765-1
• DSSTox Substance ID: DTXSID10432055
• Nikkaji Number: J118.389C
• Wikipedia: Tin(IV) acetate
• Mol file: 2800-96-6.mol

Synonyms:Tin(IV) acetate;2800-96-6;tin(4+);tetraacetate;tin (IV) acetate;Tetraacetoxystannane;tin-(IV)-acetate;TETRAACETOXYTIN;Tetraacetoxytin;Tinacetate;DTXSID10432055;YJGJRYWNNHUESM-UHFFFAOYSA-J;AKOS025293663;FT-0705097;A876810

Chemical Property of Tin(IV) acetate

Chemical Property:

• Appearance/Colour: white crystalline powder
• Vapor Pressure: 13.9mmHg at 25°C
• Melting Point: 232 - 233 C
• Flash Point: 40oC
• PSA: 105.20000
• LogP: -0.32560
• Sensitive.: Hygroscopic
• Solubility.: Soluble in acetone and benzene.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 355.955420
• Heavy Atom Count: 17
• Complexity: 25.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tin(IV) acetate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Sn+4]
• Uses: Tin(IV) acetate is used to prepare tin-based oxides (Sn-Zn-P-O), which is a negative electrodes for rechargeable lithium batteries.

Technology Process of Tin(IV) acetate

There total 24 articles about Tin(IV) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tetraphenyltin(IV) (595-90-4) + acetic acid (64-19-7,77671-22-8) → tin(IV) acetate (638-39-1,2800-96-6,14517-02-3,17856-15-4,95347-73-2)

Guidance literature:

refluxing under dry N2 for 4 h; removal of volatile material at reduced pressure, colourless crystals are obtained;

Reference yield: 98.0%

acetic anhydride (108-24-7) + diphenyltin(IV) oxide (2273-51-0) + acetic acid (64-19-7,77671-22-8) → tin(IV) acetate (638-39-1,2800-96-6,14517-02-3,17856-15-4,95347-73-2)

Guidance literature:

byproducts: benzene; mixture is refluxed for 4 h, then allowed to stand overnight at room temp.; crystals are sepd., evapn. of mother liquor yields additional amt., elem. anal.;

Reference yield: 90.0%

tin(II) acetate*2(acetic acid) → tin(II) acetate (638-39-1,2800-96-6,14517-02-3,17856-15-4,95347-73-2)

Guidance literature:

In neat (no solvent); sublimed at 150-160°C at 1E-2 Torr; elem. anal.;

DOI:10.1016/j.poly.2007.08.010

upstream raw materials:

acetic acid

tin

acetic anhydride

acetate

Downstream raw materials:

tin

tetraethyltin

1,4-diacetoxynaphthalene

acetoxytriethylstannane

Refernces

• 1、 Sharma, Malti,Bhagi, Ajay K.,Sharma, Harish K.,Priti, Ritu Kansal,Kumar, Ram,Kapoor, Pramesh N.. "Precursors for mixed metal oxide nanoparticles: Synthesis and characterization of μ-oxoalkoxides of some bivalent metals and their β-diketonates". . p. 256 - 260. Retrieved 2007/10/03.
• 2、 Reifenberg, Gerald H.,Considine, William J.. "Organotin chemistry. 16. Reactions of stannane with organic functional groups". . p. 3015 - 3018. Retrieved 2008/10/08.