Diphenyltin oxide

Base Information

• Chemical Name: Diphenyltin oxide
• CAS No.: 2273-51-0
• Molecular Formula: C12H10OSn
• Molecular Weight: 288.921
• Hs Code.: 2931900090
• European Community (EC) Number: 218-883-8
• NSC Number: 170023,55161
• DSSTox Substance ID: DTXSID501315500
• Mol file: 2273-51-0.mol

Synonyms:DIPHENYLTIN OXIDE;2273-51-0;oxo(diphenyl)tin;Diphenyltin(IV) oxide;Oxodiphenylstannane;DIPHENYLTINOXIDE;diphenylstannanone;EINECS 218-883-8;NSC 170023;Oxodiphenyltin(IV);31671-16-6;C12H10OSn;NSC55161;starbld0016595;NCIOpen2_001982;SCHEMBL313952;Diphenyltin(IV) oxide, 97%;C12-H10-O-Sn;(C12-H10-O-Sn)x-;DTXSID501315500;CAA27351;MFCD00058851;NSC 55161;NSC-55161;NSC170023;AKOS025293673;NSC-170023;LS-146553;FT-0709565

Chemical Property of Diphenyltin oxide

Chemical Property:

• Appearance/Colour: White powder
• Melting Point: 320 °C (dec.)(lit.)
• PSA: 17.07000
• LogP: 1.22280
• Solubility.: Acetic acid
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 289.975367
• Heavy Atom Count: 14
• Complexity: 171

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diphenyltin oxide, 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](=O)C2=CC=CC=C2
• Uses: Oxodiphenylstannane is a useful reagent in the synthesis of supramolecular structures. It can also be used as a catalyst in the conversion of trioses to alkyl lactates in alcohol solution.

Technology Process of Diphenyltin oxide

There total 22 articles about Diphenyltin oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(triphenyltin) oxide (1262-21-1) → tetraphenyltin(IV) (595-90-4) + diphenyltin(IV) oxide (2273-51-0)

Guidance literature:

In neat (no solvent); (Ph3Sn)2O is heated at 310°C for 2.5 h under N2 atm.;

DOI:10.1016/S0277-5387(00)84121-2

Reference yield:

bis(triphenyltin) oxide (1262-21-1) + diphenyltin (1011-95-6) → triphenylstannane (892-20-6) + diphenyltin(IV) oxide (2273-51-0)

Guidance literature:

In benzene; reaction at 20°C for 4 h;;

Reference yield:

{(iso-C4H9)2SnH}2 (6055-29-4) + diphenyltin (1011-95-6) → triphenylstannane (892-20-6) + diphenyltin(IV) oxide (2273-51-0)

Guidance literature:

In benzene; reaction in benzene at 20°C for 4 h;;

upstream raw materials:

bis(triphenyltin) oxide

diphenyltin

water

diphenyltin(IV) dichloride

Downstream raw materials:

bis(phenyl) carbonate

butyl phenyl carbonate

(C₆H₅)2Sn(PS₂(OCH₂C(CH₃)2CH₂O))2

(C₆H₅)2Sn(PS₂(OC(CH₃)2)2)2

Refernces

• 1、 El-Boraey,El-Saied,Aly. "UO2(VI), Sn(IV), Th(IV) and Li(I) complexes of 4-azomalononitrile antipyrine: Synthesis, characterization and thermal studies". . p. 599 - 606. Retrieved 2009.
• 2、 Pellerito,Scopelliti,Fiore,Nagy,Barone,Abbate,Stocco,Pellerito. "Structural investigations on diorgano- and triorganotin(IV) derivatives of [meso-tetra(4-sulfonatophenyl)porphine] metal chlorides". . p. 1573 - 1583. Retrieved 2007/10/03.