Thexyltrichlorosilane

Base Information

• Chemical Name: Thexyltrichlorosilane
• CAS No.: 18151-53-6
• Molecular Formula: C₆H₁₃Cl₃Si
• Molecular Weight: 219.614
• Hs Code.: 2931900090
• European Community (EC) Number: 672-661-9
• DSSTox Substance ID: DTXSID80570094
• Wikidata: Q82457433
• Mol file: 18151-53-6.mol

Synonyms:Thexyltrichlorosilane;18151-53-6;trichloro(2,3-dimethylbutan-2-yl)silane;Silane,trichloro(1,1,2-trimethylpropyl)-;SCHEMBL1721424;Thexyltrichlorosilane, >/=96%;DTXSID80570094;1,1,2-trimethylpropyltrichlorosilane;MFCD09953184;AKOS015837820;Trichloro(2,3-dimethyl-2-butyl)silane;Trichloro(1,1,2-trimethylpropyl)silane;CS-0373735;T2517;T71962

Chemical Property of Thexyltrichlorosilane

Chemical Property:

• Vapor Pressure: 1.39mmHg at 25°C
• Melting Point: <0
• Refractive Index: 1.448
• Boiling Point: 177.6 °C at 760 mmHg
• Flash Point: 72.5 °C
• PSA: 0.00000
• Density: 1.109 g/cm³
• LogP: 4.07790
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 217.985210
• Heavy Atom Count: 10
• Complexity: 115

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trichloro(2,3-dimethylbutan-2-yl)silane ^*data from reagent suppliers

Safty Information:

• Statements: 34-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C(C)(C)[Si](Cl)(Cl)Cl

Technology Process of Thexyltrichlorosilane

There total 4 articles about Thexyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2,3-Dimethyl-2-butene (563-79-1) + 1,1'-azobis (cyclohexanecarbonitrile) (2094-98-6) → trichloro(2,3-dimethylbutan-2-yl)silane (18151-53-6)

Guidance literature:

With trichlorosilane;

Reference yield: 77.0%

2,3-Dimethyl-2-butene (563-79-1) → trichloro(2,3-dimethylbutan-2-yl)silane (18151-53-6)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); trichlorosilane; at 120 ℃; for 23h;

DOI:10.1246/cl.1987.2247

Reference yield: 59.3%

2,3-Dimethyl-2-butene (563-79-1) + trichlorosilane (10025-78-2) → trichloro(2,3-dimethylbutan-2-yl)silane (18151-53-6)

Guidance literature:

In not given; HSiCl3 and C(CH3)2C(CH3)2 at about 50°C in presence of peroxide;;

upstream raw materials:

2,3-Dimethyl-2-butene

sulfuric acid

trichlorosilane

1,1'-azobis (cyclohexanecarbonitrile)

Downstream raw materials:

dichlorophenyl(1,1,2-trimethylpropyl)silane

Refernces

• 1、 Tobita, Hiromi,Kawano, Yasuro,Shimoi, Mamoru,Ogino, Hiroshi. "Photoinduced Direct Synthesis of Silylene-Bridged Dinuclear Iron Complexes5-C5H5)2Fe2(CO)2(μ-CO)(μ-SiHR)> from 5-C5H5)Fe(CO)2SiMe3> and RSiH3 (R=t-Bu, (CMe2)2H)". . p. 2247 - 2250. Retrieved 1987.