Methyl 4-bromo-1-naphthoate

Base Information

• Chemical Name: Methyl 4-bromo-1-naphthoate
• CAS No.: 35615-97-5
• Molecular Formula: C12H9BrO2
• Molecular Weight: 265.106
• Hs Code.: 2916399090
• Mol file: 35615-97-5.mol

Synonyms:1-Naphthoicacid, 4-bromo-, methyl ester (7CI);Methyl 4-bromo-1-naphthoate;

Chemical Property of Methyl 4-bromo-1-naphthoate

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.635
• Boiling Point: 370.765 °C at 760 mmHg
• Flash Point: 178.033 °C
• PSA: 26.30000
• Density: 1.492 g/cm³
• LogP: 3.38890
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Methyl4-bromo-1-naphthoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl 4-bromo-1-naphthoate

There total 11 articles about Methyl 4-bromo-1-naphthoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

methanol (67-56-1) + 4-bromonaphthalene-1-carboxylic acid (16650-55-8) → 4-bromo-naphthalene-1-carboxylic acid methyl ester (35615-97-5)

Guidance literature:

4-bromonaphthalene-1-carboxylic acid; With pyridine; In thionyl chloride; at 85 ℃; for 12h;

methanol; at 85 ℃; for 5h;

Reference yield: 97.0%

→ 4-bromo-naphthalene-1-carboxylic acid methyl ester (35615-97-5)

Guidance literature:

Reference yield:

oxalyl dichloride (79-37-8) + 4-bromonaphthalene-1-carboxylic acid (16650-55-8) → 4-bromo-naphthalene-1-carboxylic acid methyl ester (35615-97-5)

Guidance literature:

In methanol; 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; N,N-dimethyl-formamide;

upstream raw materials:

4-bromonaphthalene-1-carboxylic acid

dimethyl sulfate

methanol

4-bromo-1-naphthoic acid chloride

Downstream raw materials:

4-cyano-1-naphthoic acid

methyl 4-cyano-1-naphthoate

(E/Z)-4-(5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-N-(2-(ethoxyimino)ethyl)-1-naphthamide

(E/Z)-4-(5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-yl)-N-(2((2-fluoroethoxy)imino)ethyl)-1-naphthamide

Refernces

• 1、 Liu, Chengxin,Cui, Jin,Wang, Yufang,Zhang, Mingjie. "A new 2D Cu-MOF constructed from carboxylate ligands containing C-H?π interactions as a recyclable responsive luminescent sensor for VOCs". supporting information. p. 4124 - 4128. Retrieved 2021/04/06.
• 2、 -. "Preparation method of novel 5-[4-(1-carboxyl naphthyl)]-isophthalic acid". Paragraph 0019; 0020. . Retrieved 2016/10/20.