Silver formate

Base Information

• Chemical Name: Silver formate
• CAS No.: 13126-70-0
• Molecular Formula: CH2 O2 . Ag
• Molecular Weight: 152.886
• European Community (EC) Number: 236-061-7
• DSSTox Substance ID: DTXSID50156985
• Nikkaji Number: J317.822F
• Wikidata: Q28411373
• Mol file: 13126-70-0.mol

Synonyms:Silver formate;EINECS 236-061-7;13126-70-0;CH2O2.Ag;Formic acid silver(I) salt;C-H2-O2.Ag;Formic acid, silver(1) salt;SCHEMBL136497;DTXSID50156985;Q28411373

Chemical Property of Silver formate

Chemical Property:

• Vapor Pressure: 36.5mmHg at 25°C
• Boiling Point: 100.6°Cat760mmHg
• Flash Point: 29.9°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 151.90275
• Heavy Atom Count: 4
• Complexity: 7.5

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)[O-].[Ag+]

Technology Process of Silver formate

There total 7 articles about Silver formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

formic acid (64-18-6) + silver carbonate → silver(I) formate (13126-70-0)

Guidance literature:

adding Ag2CO3 to HCO2H at 0°C, stirring at room temp. for 1 h inthe dark; filtration, pptn. with Et2O, filtration, washing with Et2O, drying under vac. at room temp. in the dark;

DOI:10.1246/bcsj.73.453

Reference yield:

sodium formate (141-53-7) + silver nitrate → silver(I) formate (13126-70-0)

Guidance literature:

In methanol; in abs. ethanol, pptn.;; drying over H2SO4 (exclusion of light);;

Reference yield:

water (7732-18-5) + silver (I) ion (14701-21-4,67542-54-5) → silver(I) formate (13126-70-0)

Guidance literature:

With carbon monoxide; In perchloric acid; byproducts: H(1+); High Pressure; equilibrium reaction, p(CO)<=30 atm, 60-110°C, quick react.;

upstream raw materials:

water

silver (I) ion

formic acid

silver(l) oxide

Downstream raw materials:

diphenyldiformoxysilane

[Ag(triphenylphosphine)2(formato)]*(dichloromethane)

[2,5-Ph2-3,4-Tol2(η(5)-C4COCH3)]Ru(CO)2(η(1)-OCHO)

[(CH₃CHCHCH₂)Pd(HCO₂)(P(C₆H₄CH₃)3)]

Refernces

• 1、 Oshima, Masato,Sakamoto, Toshiaki,Maruyama, Yooichiroh,Ozawa, Fumiyuki,Shimizu, Isao,Yamamoto, Akio. "Synthesis and Properties of (η3-1-Methylallyl)palladium(II) Formates as Models of Intermediates in the Palladium-Catalyzed Reductive Cleavage of Allylic Carboxylates and Carbonates with Formic Acid". . p. 453 - 464. Retrieved 2007/10/03.