PYRIDINE-2-ALDOXIME

Base Information

• Chemical Name: PYRIDINE-2-ALDOXIME
• CAS No.: 2110-14-7
• Molecular Formula: C6H6 N2 O
• Molecular Weight: 122.126
• Hs Code.: 2933399090
• Mol file: 2110-14-7.mol

Synonyms:2-Pyridinecarboxaldehyde,oxime, (Z)-

Chemical Property of PYRIDINE-2-ALDOXIME

Chemical Property:

• Melting Point: 110-112 °C(lit.)
• PKA: 3.59, 10.18(at 20℃)
• PSA: 45.48000
• LogP: 0.88970
• Storage Temp.: Store at 0°C
• Solubility.: methanol: 0.1 g/mL, clear

Purity/Quality:

98% ^*data from raw suppliers

Pyridine-2-aldoxime 98+% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-37/38-41
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of PYRIDINE-2-ALDOXIME

There total 3 articles about PYRIDINE-2-ALDOXIME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

pyridine-2-carbaldehyde (1121-60-4) → 2-hydroxyiminomethyl-pyridine (2110-14-7)

Guidance literature:

Reference yield:

(E)-pyridin-2-aldoxime (1193-96-0) → 2-hydroxyiminomethyl-pyridine (2110-14-7)

Guidance literature:

for 30h; Irradiation;

DOI:10.1246/bcsj.56.1101

Reference yield:

→ 2-hydroxyiminomethyl-pyridine (2110-14-7)

Guidance literature:

α-Picolin, Natrium, n-Butylnitrit;

DOI:10.1007/BF00470238

upstream raw materials:

(E)-pyridin-2-aldoxime

pyridine-2-carbaldehyde

Downstream raw materials:

1-(β-phenethyl)-2-hydroxyiminomethyl-pyridinium iodide

pyridine-2-carboxylic acid amide

pyridine-2-carboxylic acid benzyl ester

octyl 2-pyridinecarboxylate

Refernces

• 1、 Janicki, Rafa?. "Synthesis, crystal structure and spectral properties of diammonium dihydrogen N-(methylene-2-pyridine)-N,N,-di-(methylenephosphonate)". . p. 35 - 41. Retrieved 2013.
• 2、 De Lijser, H.J. Peter,Hsu, Susan,Marquez, Bernadette V.,Park, Adriana,Sanguantrakun, Nawaporn,Sawyer, Jody R.. "Effect of structure in benzaldehyde oximes on the formation of aldehydes and nitriles under photoinduced electron-transfer conditions". . p. 7785 - 7792. Retrieved 2007/10/03.