Me₃SiNPPh₂CH₃

Base Information

• Chemical Name: Me₃SiNPPh₂CH₃
• CAS No.: 51649-11-7
• Molecular Formula: C₁₆H₂₂NPSi
• Molecular Weight: 287.417
• Mol file: 51649-11-7.mol

Synonyms:Me₃SiNPPh₂CH₃

Chemical Property of Me₃SiNPPh₂CH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Me₃SiNPPh₂CH₃

There total 2 articles about Me₃SiNPPh₂CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trimethylsilylazide (4648-54-8) + diphenyl(methyl)phosphine (1486-28-8) → Me3SiNPPh2CH3 (51649-11-7)

Guidance literature:

at 130 ℃; for 6h;

Reference yield:

→ Me3SiNPPh2CH3 (51649-11-7)

Guidance literature:

DOI:10.1016/S0022-328X(00)82266-4

Reference yield: 81.0%

tungsten(VI) chloride (13283-01-7) + Me3SiNPPh2CH3 (51649-11-7) → {W2(N)Cl9}2(2-)*2PCl(CH3)(C6H5)2(1+)={W2(N)Cl9}2{PCl(CH3)(C6H5)2}2

Guidance literature:

In dichloromethane-d2; addn. of a CD2Cl2 soln. of (CH3)3SiNP(CH3)(C6H5)2 to a soln. of WCl6 in CD2Cl2; sealed in a NMR tube; 6 days at 22°C; anhydrous and anaerobic conditions;; filtration; washed with CH2Cl2; dried under vac.; elem. anal.;;

upstream raw materials:

trimethylsilylazide

diphenyl(methyl)phosphine

Downstream raw materials:

C₂₀H₂₆NO₃PSi

C₂₄H₂₆NO₃PSi

trimethylsilyl isocyanate

N-phenyl-N'-(trimethylsilyl)carbodiimide

Refernces